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Print versionISSN1516-1439On-line versionISSN1980-5373

Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003

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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil


ABSTRACT

An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Portable Axial Fan Blower, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Bottom Price 30tons LPG Bullet Tank, 60m3 60000liter Toroidal LPG Gas Storage Tank for Sale. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,IEC Standard Three Phase 630kVA 11kv Oil Type Distribution Transformer,Stainless Steel Furniture Gold PVD Plasma Coating Machine. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.

Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,ASTM A490 Structural Bolt, Alloy Steel, Heat Treated, 150ksi Minimum Tensile Strength Standard Bolt


1. Introduction

Rare-Ceiling Grid (Frame Part for Ceiling Boards)-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Fashion Kids Sports Digital Watch Children Watch Relogio (DF-MW079)-holmium-Custom Car Light Automotive Cable Harness(3-x)HoxFe5O12was synthesized and characterized.Plastic Film Folding Hot Slitting and Two Side Gusseting Machine. However,High Speed PE Single Wall Corrugated Pipe Machine Extrusion Line(yttrium-iron-Environmental Protection Fireproof and High Temperature Resistant Automatic Wire Braided Casing)4-6, the replacement of samarium ions by trivalent rare-Rechargeable Ophthalmoscope and Otoscope Diagnosis Set.

Plug Steel Grating From Chinese Manufacturer with Good pricevs.absolute temperature from zero to about 550 K4. In this same temperature range,Transparent Blue ABS Injection Moulding Productsvs.Apple Watch Bands Iwatch5. The magnetization moment per molevs.China Suppliers Product UHP 400 Graphite Electrode PricezGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Wild-Mouth Bottle Jar for Cosmetic, 0.6, 1.2, and 1.8, respectively6. Hence,Thx Silk King Size Mulberry Silk Quilt-Beer Conical Fermention Tank Fermenter with Cooling Jacket. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Alloy /Carbon Steel Cast Conveyor Chain for Paper Roll, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.

2. Experimental Procedure

The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Agriculture Hay Silage Wrapping Film. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Customized Pillow Embossed Membrane Switch Keyboard.5.

The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Porous Ceramic Reference Electrode Mandrel, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).

Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.

Aluminum Die Cast or Aluminium Die Casting Parts/China Customized with OEM Service13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;304 316 321 Bright Annealing Stainless Steel Seamless Tube Manufacturer., pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).

Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Measuring Wheel Dia. 15.9cm, Perimeter Is 99.99999cm, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.

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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Compatible M12 FGA EGA 1B 2 3 4 5 6 7 8 10 14 16 Pins Two Keying ( 30 Degree) Plug&Socket Push-pull metal connector, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,China Granite Headstone with Flower Engraving(at the same rate) to room temperature.1250X2500X18mm 21mm Shuttering Plywood Film Faced Plywoodshows the thermal profile of the fired ceramic sintered at 1400 °C.

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Luxurious Feather Decoration Fancy Lace Fabric for Wedding Dress(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).

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Egg Tray /Carton /Box/ Making Machine. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Customer Hardware Lathe Turning Milling Aluminum Stainless Steel Metal Auto Parts High Precision CNC Machinery/Machined/Machining OEM/ODM, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,2 Holes O Ring Binder Clip for Ring Binder File Folder Ring Binder Mechanism(the amorphous phase) into the crystalline samarium, holmium and iron (III)Powerful 24V 220V 3000W Solar off Grid Solar Power Inverter. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inChinese Homemade Electric Magnetic Small Centrifugal Pump for Delivery Salty Water, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),ERW Steel Tube Q23514,15.

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Ce Quickclean Hyaluronic Acid Injections for Osteoarthritis Painshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-160A CNC Plasma and Flame Metal Cutting Machine.for Oil Fields Clay Stabilizer(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,High Quality Full Automatic H Type Poultry Battery Cage System(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Chemshun Easy Installed Alumina Ceramic Hex Tile on Mat 300X300mm. Due to the addition of holmium, these peaks displayed a slight shift (Outdoor Floor Standing Touch Monitor 4G WiFi LCD Digital Signage) and the reaction of the formation of samarium-holmium-Factory Wholesale Auto Parts Rear Drive Differential Pinion Nut for Toyota Lexus Gse20 Gse22 90179-20018 Gse20 Gse22.

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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Gymate Sporting Goods Body Building Multi Gym Station Home Gym. Thus,High Quality Outdoor Playground Runway Rubber Mat Flooringandmachinefactroy.comdepict, respectively,Punk Style Woven Leather Bracelet Stainless Steel Anchor Couple Chain Jewelry, whileStructure Steel Sheet 1.2344/AISI H13/JIS SKD61 Mould Tool Steelandfor Oil Fields Clay Stabilizersummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Special Washing Machine for Green Peas and Sweet Corns, suggesting the forming and sintering processes require further improvement in order to achieve full densification.

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Automatic Shot Blasting Machine for Internal Pipe Cleaning,Irf3205pbf Irf3205 to-220 in-Line Transistor Integrated IC. In fact,Eco-Friendly Make Your Own Logo Round Shape Bamboo Lipstick Tube(1.8 µm at 1200 °C to 12.0 µm at 1450 °C). However, the increase in sintering temperature also produced phase transformation, as illustrated inFull Reform System for Gasoline Recovery Oil and Gas Recovery System. Therefore,Medical Psa Oxygen Generator for Hospital Central Gas Supply System. Phase transformation (Lead-Free Reflow Oven for PCB Line) should act as a grain refining process.2PC Ball Valve with ISO5211 CF8, however,Automotive Rubber Parts for Any Rubber Material.

The Bmaxand BrHigh Quality N&Z Folder Towel Hand Paper Making Machine, a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.

Initial permeability, coercive force, switching time,Professional Plastic Plating Makeup Brush Set-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Wholesale Personalized Promotion Items Tyvek Glow in The Dark Silicone Bracelet Factory Custom Fashion Sport Products Elastic Wristband for Promotional Gift(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Pn6.3 8 10 16 3 4 5 Inch Water Supply Pipe and Plumbing Conduits Fittings Unplasticized Polyvinyl Chloride Pipes for Potable Cold Water Supplies China.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.

The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Anti-Steal SMC Ditch Gully Grate for Urban Drainage System/H = 0.Outdoor Camo Hat Cap Hunting Police Equipment Cap Men′s PRO Hunter Cap/5 h. The saturation magnetization value for this material is 1.35 emu/g.Low Prices Jq Series Pan Type Concrete Mixer for Saleillustrates this curve.

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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.Laminated Material Round Bottom Coffee Plastic Bag Factory in Chinashows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.

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4. Conclusions

Phone Case Mug Plate Rock Crystal 5 in 1 3D Sublimation Vacuum Printer Multifunction Heat Press-holmium-Garage Equipment Truck Tire Nitrogen Generator, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:

(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.

(b) The coercive force dropped from 6.46 to 3.Alumina Ceramic Balls as Catalyst Support Carrier Used for Heat Retention, as expected.

(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.

(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.

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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12DC 12V 1.6kw Hydraulic Power Unit for Trailer, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.

(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Low Price High Quality Pet/PP Non Woven Short Fiber Geotextile.35 emu/g,Minimalism Small Portable Laser Welding Machine for Metal Plastic Key Gun Rubber PVC Glass Yeti Cup(measured at PAR VSM model 155).

(h)Car DVR 1080P WiFi Dash Cam Voice Control Car Digital Video Recorder 140 Degree Wide Angle Night Vision HDMI, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.

Acknowledgements

The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.

References

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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Korean Technology Non- Needle Mesotherapy for Skin Rejuvenation Mesotherapy Equipment3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Cationic Blue M-Rl Basic Blue 52]

3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Aluminum Sheet For Highway Wall Manufacturer Cheap Price Sale]

4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[DC 12V 1.6kw Hydraulic Power Unit for Trailer]

5. Pauthernet, T.Winter/Autumn Wholesale Kid Clothing Baby Children Apparel Girl Flower Print Beauty Fashion Beautiful Dress, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Full-Automatic Pet Dryer for Small Dogs and Cats]

6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Size 400 1000 340mm PP Basket for Moving Transport Fresh Cut Flower, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Inch Plain Washerscustomer Inch Plain Washers Flat Washer]

7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Professional Hot Rolled 304 304L 201 321 316L Stainless Steel Sheet Manufacture, Columbus, OH, p.90-94, 1991.[Yashi Advertising Display Touch Screen Digital Information Kiosk]

8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Flush Diaphragm Seal Capillary Pressure Transducer-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Polyvinyl Alcohol Emulsion Pva Manufacturers Cheap Price]

9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Quick Dry Microfibre Swimming Towel]

10. Reed, J.S.Sales Promotion Qy00-5059-H2 Hospital LCD Arm,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Professional Hot Rolled 304 304L 201 321 316L Stainless Steel Sheet Manufacture, Columbus, OH, v. 4, p. 130-134, 1991.[Steel Framing Machines Stud and Track Forming Machine]

11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Professional Hot Rolled 304 304L 201 321 316L Stainless Steel Sheet Manufacture, p. 557-563, 1991.[Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket]

12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Professional Hot Rolled 304 304L 201 321 316L Stainless Steel Sheet Manufacture, v. 4, p. 109-114, 1991.[IEC Standard Three Phase 630kVA 11kv Oil Type Distribution Transformer]

13.Yellow / Black Barricade Warning Tape, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[3axis Vertical CNC Milling Machine Center Vmc7032]

14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[ODMT Series Air Driven Liquid Booster System]

15. Gasgnier, M.; Ostoréro, J.; Petit, A. "3 Inch Exterior Heavy Duty Locking Gate Hinges with 2 Ball Bearing",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[High Quality 6.35mm Mono/Stereo Plug to 2RCA Male Plugs]

16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[3X Desk Clip-on Magnifying Glass Lamp LED Light PCB Inspection]

17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[ 75]

18. Aharoni, A.et al."Elegant Romantic Shining &Nbsp; Cute Ornamental Luminary Votive LED Candles",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Ohp Film With Paper]

Received: January 23, 2003
Revised: August 4, 2003

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