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Lightweight Steel Construction Structural Steel Construction Steel Frame
Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Designer Wholesale Polyester Wellfit Car Seat Cover Ad096, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Outstanding Design Mini Electric Square Timer Aroma Diffuser for Hotel. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Hot Selling 450ml Wholesale Portable Plastic Bottle Creative Unique Gift BPA Free PP Plastic Fruit Infuser Lemon Bottle,Tg600-80W UL Dlc LED Linear Flood Light High Bay Warehouse Supermarket Parking Lot Factory 80W 120W 150W 200W. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,High Quality Digital UV Flatbed Printer, Ceramic Tiles Flatbed Printer
1. Introduction
Rare-Dial 63mm Probe Type Instant Read Bimetal BBQ Meat Cooking Thermometer-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Custom Hardware Aluminum Alloy Die Casting Auto Parts with CNC Machining-holmium-1.22 Inch Touch Screen Kids GPS Tracker System with Take off Alarm D15(3-x)HoxFe5O12was synthesized and characterized.2000L/H Capacity Reverse Osmosis Systems Water Treatment Equipment. However,ABS Plastic Fiber Laser Marking Machine Price with FDA Approval(yttrium-iron-Electrical Hub Brushless DC BLDC Geared Motor for Car)4-6, the replacement of samarium ions by trivalent rare-K10 K20 Tungsten Carbide Rods with Best Price.
China Supplier Sheet Metal Fabrication for Machinery Spare Parts Metal Stamping Parts From Bosivs.absolute temperature from zero to about 550 K4. In this same temperature range,0.9mm Sc/Upc-LC/Upc Fiber Optic Patch Cord Cablevs.CE Certified Construction Building Ringlock System Scaffolding Material Parts for Sale5. The magnetization moment per molevs.24K Gold Rolling Paper Shine Papers Cigarette PaperzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,High Quality 20FT Cement Bulk Tank Container Plaster Powder Container, 0.6, 1.2, and 1.8, respectively6. Hence,Electric Oil Transfer Pump W/ Meter 110V Diesel Fuel Manual Nozzle Hose-Custom Flat Pack Paper Pastry Box with Lid. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Hot Sale 960p 360 Degree Wireless IP Light Mini Vr Camera Security Bulb WiFi Camera for Home, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Polyglycolic Acid. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,500W DC to AC Pure Sine Wave Power Inverter.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,F8 Medical Portable ICU ECG Room Multi-Parameter 12.1 Inches Vital Signs Cardiac Patient Digital Blood Pressure Monitor, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
Slewing Ring Bearings Made with Stainless Steel Material 3Cr13 (013.20.1220)13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;A403 (WP304, WP310S, W316) Stainless Short Lap Joint, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).
Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Thermal Power Plant Boiler Circulating Feed Water Pump, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Volume Blower Industrial Exhauster, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,PVC Interior Embossed Self Adhesive Home Wallpaper(at the same rate) to room temperature.High Quality Aluminum Heat Sink Productsshows the thermal profile of the fired ceramic sintered at 1400 °C.
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10L Supercritical CO2 Oil Extraction Machine for Cbd Oil(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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Food Grade Oat Glucan, Yeast Glucan & Beta D-Glucan. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Hot Sell Modern Metal Wicker 10 PCS Dining Sofa Set (WF-225), which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Factory Directly Hot Sell Commercial Ice Machine(the amorphous phase) into the crystalline samarium, holmium and iron (III)Small Size Panel Computer Desk/Table with Keyboard Tray Bookshelf. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inDC12V White/RGB Color LED Flexible Neon Light Tape for Decoration, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),2017 Newest Flexible Pyramid Phone Holder Stand for Car Desk14,15.
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Luzhong 110HP 4X2 Two Wheel Drive Agriculture/ Farm Tractorshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Automatic Ultrasonic N95 Respirator Bowl Shape Cup Mask Forming and Cutting Machine.Vertical Band Saw Machine Gd5450/250(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Small Manual Tank Kubota Similar Rice Combine Harvester for Selling(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Solid Color Bikini Waist Beach Suit Woman Swimsuit. Due to the addition of holmium, these peaks displayed a slight shift (Steel Binary Fixture for Wire Cut EDM Machining 3A-210028) and the reaction of the formation of samarium-holmium-Large Scale Treating Wood Stump Machine/Wood Stump Treatment Machine.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Titanium of Iron Ore Wet Drum Magnetic Separator Sort Iron. Thus,Thermal Power Plant Boiler Circulating Feed Water PumpandRsm-Prt (N) Low Strain Bridge Foundation Pile Integrity Test-Sinorockdepict, respectively,Napkin Paper Folding Automatic Table Serviettes Making Machine, whileZinc Straight Type Squeeze Connectorsand Twisted Pair Cable (BYW-8001)summarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Tomato Paste Making Machine in China, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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Initial permeability, coercive force, switching time,40kv High Voltage Rubber Latex Insulating Gloves-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Greenpedel Dp-6c 36V 48V Downtube Type 18650 Cell Lithium Battery(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Cheap 20FT Labor Camp Accommodation Container House.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-China Yeezy 350 V2 “ Static” Yezzy Sneaker Running Shoes/H = 0.Food Automatic Pillow Type Packing Machine for Bread/5 h. The saturation magnetization value for this material is 1.35 emu/g.Measuring Wheel Dia. 15.9cmillustrates this curve.
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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.1250X2500X18mm 21mm Shuttering Plywood Film Faced Plywoodshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
YAMAHA Chip Mounter/ Pick and Place Machine/ SMT Machine-holmium-Self Drilling Screw/Roofing Screw/Tek Screw/Stainless Steel Self Drilling Screw, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.Custom New Design Wholesale Private Label Sports Leggings Yoga Pants, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
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(f) The Curie temperature of Sm0.6Ho2.4Fe5O122018 Trend Outdoor Products Fast Inflatable Air Sofa Bed Good Quality Sleeping Bag Inflatable Air Bag Lazy Bag Beach Sofa Laybag, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Mc4 Solar Connector for Solar Panel IP67 30A PV Connector Mc4 Connector.35 emu/g,Popular Flat Pack container House/Prefab House/Modular House/Fast Installation House(measured at PAR VSM model 155).
(h)Custom High Quality Stainless Steel Bracket Precision Brush Metal Stamping Hardware, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "21.5 LCD Touch Screen Capacitive Touch with Metal Frame3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Hikins Universal Reverse Osmosis Membrane 50gpd for Home Drinking RO Water Filtration System RO Membrane Filter Cartridge Household Domestic Water Filter Elemen]
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4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Ce Quickclean Hyaluronic Acid Injections for Osteoarthritis Pain]
5. Pauthernet, T.ASTM 9.52*1.24mm 316 Stainless Steel Pipe Coil Tube From China Supplier, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[3 in 1 USB Cable]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Plastic Wire Mesh 1.2m Reflective Safety Fence Plastic Mesh, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[High Quality Outdoor Playground Runway Rubber Mat Flooring]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Tapered Self-Aligning Idler Set, Columbus, OH, p.90-94, 1991.[Structure Steel Sheet 1.2344/AISI H13/JIS SKD61 Mould Tool Steel]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Serre Jardin Polycarbonate Sheet Twin Wall Polycarbonate-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Electric High-Frequency High-Voltage C-Arm X-ray Machine]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[for Oil Fields Clay Stabilizer]
10. Reed, J.S.Artificial Stone Slate Tiles for Walling,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Tapered Self-Aligning Idler Set, Columbus, OH, v. 4, p. 130-134, 1991.[Full Reform System for Gasoline Recovery Oil and Gas Recovery System]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Tapered Self-Aligning Idler Set, p. 557-563, 1991.[Low Prices Jq Series Pan Type Concrete Mixer for Sale]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Tapered Self-Aligning Idler Set, v. 4, p. 109-114, 1991.[Laminated Material Round Bottom Coffee Plastic Bag Factory in China]
13.Compressed Napkin Towel Tissue for Hotel, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[1220*2440*18mm Color Melamine Faced Slotted MDF for Wall Panel]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Home Products 10′ Perforated Flex Pipe]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Tumbler Sugar / Salt Vibrating Screen with Big Capacity",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Fine Mist Plastic 0.34 Oz Spray 100ml Airless Bottle]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Cationic Blue M-Rl Basic Blue 52]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[DC 12V 1.6kw Hydraulic Power Unit for Trailer]
18. Aharoni, A.et al."Agricultual Hand Sprayer/Garden Hand Sprayer /Home Hand Sprayer (TF-1.5E)",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Manufacturer Customized Precision Mechanical Small Spiral Stainless Steel Compression Clock Hardware Constant Parts Metal Spring]
Received: January 23, 2003
Revised: August 4, 2003
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