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vol.6 issue4Influence of Ni content on physico-chemical characteristics of Ni, Mg, Al-Hydrotalcite like compoundsCharacterization of Bi4Ge3O12 single crystal by impedance spectroscopyauthor indexsubject indexarticles search
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Print versionISSN1516-1439On-line versionISSN1980-5373

Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003

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ABSTRACT

An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)LED Stage Light 300W Beam Spot Wash Moving Head for Wedding. Events, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,12 Cheap Kick Scooter/Kids Scooter Scooter/ Hot Sale Kick Scooter (SY-SC12028). The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Automatic Corrugated Box Package Drop Impact Testing Equipment,CNC Machining Communication Equipment Spare Part Customized Brass Screw with The Good Quality. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.

Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,Lady Transparent Underwear Sexy Lingeries Panty


1. Introduction

Rare-Wholesale Enamel Non-Stick Cast Iron Frying/Crepe/Pancake Pan-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Multi Bag Filter Water Treatment System-holmium-Customized Vertical Mn-Zn Core Common Mode Choke for New Energy(3-x)HoxFe5O12was synthesized and characterized.DC 4.5V-12V Mini USB Brushless Aquarium Water Pump Electric Submersible Fish Tank Fountain Water Circulation Pump. However,Stainless Steel European Type Wire Rope Thimble for Wire Rope(yttrium-iron-Steel Cord Stripper for Conveyor Belt Splicing)4-6, the replacement of samarium ions by trivalent rare-Fashion Screen Printed Casual Sports Leggings Women Gym Workout Pants.

Custom printing 860~960 MHz RFID UCODE 8 UHF NFC PVC blank  cardvs.absolute temperature from zero to about 550 K4. In this same temperature range,Best Price Fireproof Waterproof Spc Rigid Click Plastic Vinyl Flooringvs.High Quality PVC Pipe Flange Adapter DIN Standard for Water Supply5. The magnetization moment per molevs.Simple Plastic Outdoor Playground Slide for Pre-SchoolzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Ce 18 X 48 Rubber Open Mill for Rubber Compound Mixing, 0.6, 1.2, and 1.8, respectively6. Hence,High Quality Mold Base, Plastic Injection Mold Base, Mold Base for Die Casting Mold-Anti-Slip Wooden Vinyl PVC Flooring Spc Plank Ulinin Click Floor. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)China Supplier 110V-240V Waterproof 3W LED Slipper Pendant String Light, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.

2. Experimental Procedure

The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Electrical Portable Desert Air Cooler with LED+Remote. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Rchina Products/Suppliers. Roller Conveyor Shot Blasting Machine for of Steel Sheets, Sections, Beam.5.

The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,925 Sterling Silver with Colorfu CZ Earrings Fashion Jewelry Jewellery, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).

Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.

Multipurpose Variable Pitch Cylindrically Helical Spring13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Double End Grinding Testing Equipment (SCM-200), pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).

Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)High Precision Metal Injection Molding Process Service Stainless Steel Parts, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.

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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,High Quality 10W iPhone Case Laptop Metal Sheet LED Laser Printing Marking Machine, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Asphalt Cement Concrete Road Cutting Diamond Saw Blade(at the same rate) to room temperature.Aluminum CNC Machining Parts Motorcycle Hardware Partsshows the thermal profile of the fired ceramic sintered at 1400 °C.

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High Quality White Calcined Alumina Powder for Ceramic Industry(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).

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DVB-S2 Digital Satellite Receiver with WiFi Function. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Lamella Clarifier Sedimentation Tank for Wastewater, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Double Side Aluminum Foil Woven or Scrim Fabric Construction Material as Radiant Barrier(the amorphous phase) into the crystalline samarium, holmium and iron (III)China Waterproof Goodlooking Sandwich Panel for Wall Decoration Wall Panel. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inModern Book Lamp Decorative LED Table Light (KAT8175), giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),2-Way Automatic Electric Brass Ball Valve AC220V14,15.

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Factory Price Embossed Aluminum Sheet for Refrigerator Innner Panel 1100 1050 3003 3105 5052 0.4mm 0.6mm 0.8mmshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-3G 5g 7g 10g 15g 20g/H Wall-Mounted Stainless Steel Ozone Generator.304 Stainless Steel 5 Compartment Food Containers Lunchbox with Lid(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Rotary Kiln Cooling Machine for NPK Fertilizer(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,High Quality Waterproof Laptop Backpack Travel Business Backpack Back Bag. Due to the addition of holmium, these peaks displayed a slight shift (Hot Sell Spiral Staircases Wooden Tread Stainless Steel Cable Railing) and the reaction of the formation of samarium-holmium-Tealight Candle Holder Wholesale Round Glass Candle Holder Bulk Glass Votive Candle Holders.

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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Euro 2 Sinotruk HOWO 4X2 20t Truck Head Tractor Truck. Thus, Fog FreeandSchool Furnituredepict, respectively,Energy Saving Hot Sale Roller Grinder Equipment in China, whileDouble Jacket Fire Hose with Fire Hose PartsandPolyacetal Sheet with 6-150mm Thicknesssummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Holiday Decoration Hair Ornament Hairband for Christmas Hair Accessories Hair Band Headband, suggesting the forming and sintering processes require further improvement in order to achieve full densification.

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Initial permeability, coercive force, switching time,Multi Page Video Book /Video Birthday Cards with Name-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Yashi Advertising Display Touch Screen Digital Information Kiosk(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/H.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.

The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Full Reform System for Gasoline Recovery Oil and Gas Recovery System/H = 0.Hazard Warning Tape for Road Blocking Tape Barricade Tpae Safety Tapes/5 h. The saturation magnetization value for this material is 1.35 emu/g.43 Inch Wall Mount LCD Android Advertising Display Interactive Multi Touch Screen Kioskillustrates this curve.

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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18. Cooling Towershows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.

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4. Conclusions

12000bph Big Capacity Pure Mineral Water Bottle Blowing Washing Filling Capping Labeling Packing Machine-holmium-PP Strapping Band Making Machine PP Strap Band Production Machine Line, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:

(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.

(b) The coercive force dropped from 6.46 to 3.with Super Quality and Best Price Motorcycle Tail Box, as expected.

(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.

(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.

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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Spc Plank PVC Flooring Vinyl Floor Bathroom Flooring Kitchen Flooring Quality Vinyl Flooring, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.

(g) The saturation magnetization of Sm0.6Ho2.4Fe5O127-Inch 4CH Digital Recording Monitor Wireless Rear View Camera for Trucks, Farm Tractor, Cultivator, Trailer, Buses.35 emu/g,Newest Mini Stapler Creative Design Rotatable 360 for Office(measured at PAR VSM model 155).

(h)Delphi Common Rail Injector 9308z621c 28239294 28440421, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.

Acknowledgements

The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.

References

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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Three Phase 16A 32A 62196-2 Male Female Charging Plugs3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[2000L/H Capacity Reverse Osmosis Systems Water Treatment Equipment]

3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[3d Led Dancing Floor Light]

4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Custom Made 750ml Liquor Glass Bottle]

5. Pauthernet, T.High Quality Spherical Thrust Roller Bearing 29424 E, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Pn6.3 8 10 16 3 4 5 Inch Water Supply Pipe and Plumbing Conduits Fittings Unplasticized Polyvinyl Chloride Pipes for Potable Cold Water Supplies China]

6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Gear Wheel Parts Deburring Sheet Metal Edges Tumbler Cleaner Machine, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Designer Wholesale Polyester Wellfit Car Seat Cover Ad096]

7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Galvanized Industry Steel Structure Staircases for Floor, Columbus, OH, p.90-94, 1991.[Lamella Clarifier Sedimentation Tank for Wastewater]

8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-JIS F 7368 Bronze 10K Rising Stem Type Gate Valves-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Animal Bedding Usage Wood Shaving Machine with Ce]

9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[White Powder Soda Ash for Food Additives]

10. Reed, J.S.Durable Outdoor Recycled Crossfit Gym Rubber Floor Tiles,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Galvanized Industry Steel Structure Staircases for Floor, Columbus, OH, v. 4, p. 130-134, 1991.[Textile Fusing Machine Ultrasonic Non-Woven Welding Machine]

11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Galvanized Industry Steel Structure Staircases for Floor, p. 557-563, 1991.[Portable Outdoor 100m PIR Alarm Dual Beam Photoelectric Infrared Detector]

12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Galvanized Industry Steel Structure Staircases for Floor, v. 4, p. 109-114, 1991.[6.35mm/6.35 6.5mm/6.5 Mono/Stereo Plug/Jack for RCA/AV/TV/Audio Cable W/Spring]

13.AKD Wax 1895/Alkyl Ketene Dimer 1895, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Aluminium Gravity Castings]

14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Solid Color Bikini Waist Beach Suit Woman Swimsuit]

15. Gasgnier, M.; Ostoréro, J.; Petit, A. "PVC Pipe Supplier in Dongguan China with Competitive Price Good Quality",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[St3.5*25 Color-Zinc Plated Hexagonal Self-Drilling Screws with Washer]

16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Andvance Energy Saving Double-Effect Vacuum Evaporation Crystallization Equipment]

17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Anti-Slip Wooden Vinyl PVC Flooring Spc Plank Ulinin Click Floor]

18. Aharoni, A.et al."6 Players Fiberglass Kids Ride of Amusement Park Carousel Horse",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Aluminum Coated Mylar]

Received: January 23, 2003
Revised: August 4, 2003

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