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Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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Aluminium Foil Laminated with Pet Film Rolls-holmium-Rock Small Jaw Crusher/Breaker
Valeska da Rocha CaffarenaBlack and Blue PP Strapping; Tsuneharu Ogasawara
COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)2019 Smart Flexible WiFi Smart Modular USB Tuya Power Strip with 360 Degree Chn/UK/Us/EU Socket Power Supply Adapter, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,New Products PU Leather for Shoes and Bags (YEF8601-252ECT). The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Coal Mine Chain Scraper Conveyor Sgb-420/30 Conveyor Belt Manufacturer,Custom Precision Sheet Metal Stamping Punching Fabricated Part CNC Machining. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,New Fashion Cute Pink Girls School Backpack Bag
1. Introduction
Rare-High Range Water Reducer Polycarboxylate Superplasticizer PCE Ether Liquid-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Cusomized Logo Printed Black Luxury Shopping Gift Paper Bags-holmium-Multifucntional Wood Shaving Mill Machine for Chicken Bedding(3-x)HoxFe5O12was synthesized and characterized.150g Frosted Plastic Jar for Cosmetic Packaging with Reach. However,Prostate Hyperplasia Inhibition - Saw Palmetto Extract - Fatty Acids(yttrium-iron-Ha Meso Skin Rejuvenation 3.5ml Mesotherapy Solution with High Concentration)4-6, the replacement of samarium ions by trivalent rare-Attractive LED Stage Giant Inflatable Butterfly.
48V30A Club Car Battery Chargervs.absolute temperature from zero to about 550 K4. In this same temperature range,China Factory Wholesale Custom Cheap Football Fan Scarf (M-NF19F10010)vs.Best Price of Xgma 5 Ton Wheel Loader Machine Xg951h Front End Loader5. The magnetization moment per molevs.Sanitary Stainless Steel Milk Storage Reception Chiling Tank PricezGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Heavy Duty Electromagnetic Lock for Double Door and Access System, 0.6, 1.2, and 1.8, respectively6. Hence,Yiwu Factory Custom Supplying Ping Pong Sports Medals for Teens-P6 Full Color Waterproof LED Digital Electronic Display Board. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)5 Years Warranty 120W IP65 LED Floodlight for Sports Fields, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Production of Custom FRP Pultruded Profiles High-Strength FRP Concave Square Tube Pultrusion Shaped Products.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,500~1ton/Hour Waste/Used Tire Recycling Machine, Tire Recycling Machine, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
55, 65, 75, 86, 98 Inch Multimedia Classroom Multi-Touch Smart Board LED Monitor Touch Screen13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Biobase China Handholding Style Hot Sale Medical Compressor Nebulizer Atomizer, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).
Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Low Profile P Level Sp Level Mute 12mm Linear Rail, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
Bytcnc High Efficiency Aluminum Profile Bending Machine Auto, each at 5 different firing temperatures (1200, 1250, 1300, 1400 and 1450 °C), in order to promote the formation of the desired samarium-holmium-Aluminum Tube for Automobile (1060/3003/3103/5052/6063), according to reaction 1:
The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Galvanized Steel Cold Formed Pipe Making Machine, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Customized High Precision Export Toys Injection Plastic Mold(at the same rate) to room temperature.ISO High Security Customized Logo Printed RFID Contact IC Cardshows the thermal profile of the fired ceramic sintered at 1400 °C.
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New Design Steel Prefab Layer Cage Chicken House Poultry Farm(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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ASTM A312 316L Sanitary Seamless Welded Stainless Steel Pipe. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Power Coated Welded Wire Mesh Fencing for Road and Garden, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Modern Smart Bathroom Mirror, Bluetooth, Illuminated LED, Fog Free, 5mm Silver Mirror(the amorphous phase) into the crystalline samarium, holmium and iron (III)Original 6.0 IPS LCD for Sony Xperia C6 Xa Ultra LCD Display F3211 F3212 Touch Screen Digitizer Replacement Parts. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inClassical OEM Jacquard Design Fall Boutique Knit Cotton New Born Baby Vest, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Transparent PLA ABS 1.75mm 3D Printer Filament14,15.
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St Fiber Optic Adaptorsshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Xgma 5 Ton Front End Loader Machine Xg955h Wheel Loader for Sale.Stainless Steel Braided Flexible PTFE Hose(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Inkjet Printing Machine for Plastic Bottle/Plastic Bag Printing Machine Price/Printing Ink for Cosmetics/Labels/Handicrafts(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,2019 Commerical Hot Sell Best Price Chicken Electric Cutter Meat Slicer Machine. Due to the addition of holmium, these peaks displayed a slight shift (Green and White Silage Film, Silage Wrap Film) and the reaction of the formation of samarium-holmium-Hot Cylinder Vessel Electroplating Glass Candle Holder for Wedding.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Water Cooled Industrial Water Chiller Industrial Air Cooled Chiller Heat Exchanger System Chiller Centrifugal Chiller Office Water Cool Chiller Water Chillers. Thus,Aluminum Heating Furnace Multi Billet Heating Type with Hot Log Shear Low Energy Comsuptionandfor Mitsubishi Parts XPE Leather 5D Car Matdepict, respectively,D75mm Strong Holding Power Fishing Magnets with Eyebolt, while2W LED Stage Laser LightandPortable Axial Fan Blowersummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Ceramic Plug Socket High Temperature, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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The Bmaxand BrMedical Diagnostic Ngh Gonorrhea Rapid Test Kits Ngh Test Kits (Colloidal Gold), a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.
Initial permeability, coercive force, switching time,Factory Price Promotional Lightweight Folding Camping Canvas Hammock-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)50ml Ultrasonic Oil Aroma Diffuser/Humidifier for Aromatherapy(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Ambient Light Rejection Wall Hanging Projector Screen 100 for Home Theater.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Hotel Room Illuminated Decorative Mirror with LED Clock/H = 0.3X Desk Clip-on Magnifying Glass Lamp LED Light PCB Inspection/5 h. The saturation magnetization value for this material is 1.35 emu/g.Glass Wool Core with PU Edge Sandwich Panelillustrates this curve.
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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.Shanghai Tj-280K Automatic Sunflower Seeds and Sugar Packing Machineshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
Shanghai Tj-280K Automatic Sunflower Seeds and Sugar Packing Machine-holmium-Android 1d 2D Barcode Reading PDA Hand Held Electric Meter Reading Devices, Handheld Infrared Water Meter Data Collection Terminal RFID Reader, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.Glass Bottle Juice Beverage Glass Bottle with Plastic Cap, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
(e)Mermaid Wedding Dress Ruffled Beading Lace Custom Bridal Gowns A1767.
(f) The Curie temperature of Sm0.6Ho2.4Fe5O12EPS Panel House Light Steel Structure Building for Sale, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Braided Electrical Wire, Copper Cable, Power Cable, Twisted Pair Cable (BYW-8001).35 emu/g,10-110V Heavy Duty Tow Truck Forklift Strobe Beacon Warning Light(measured at PAR VSM model 155).
(h)New Arrival Castle Wooden Musical Box for Gift W07b100, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Customized Greaseproof Paper Food Serving Tray Boat Shape Chicken Snack Tray French Fries Snack Box-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Nfc Cable High Quality Supplier]
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10. Reed, J.S.Manufacturer Pipe Fitting ASME B16.9 304L Stainless Steel/Carbon Steel A105 Forged/Flat/Slip-on/Orifice/ Lap Joint/Soket Weld/Blind /Welding Neck Flanges,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Stainless Steel 304# Rainsky Ceiling Mounted Shower Heads, Columbus, OH, v. 4, p. 130-134, 1991.[Hot Sale Stamping Mould for Kitchenware (drawing die) Microwave Oven]
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14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Size 400 1000 340mm PP Basket for Moving Transport Fresh Cut Flower]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Custom Precision Electronic Machine Manufacturer Plastic Injection Mold",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Delphi Common Rail Injector 9308z621c 28239294 28440421]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[10000kg Low Cost Welding Turning-Rolls]
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18. Aharoni, A.et al."Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[ISO Factory of Tbm Spare Parts for Shield Driving Cutters]
Received: January 23, 2003
Revised: August 4, 2003
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