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vol.6 issue4Influence of Ni content on physico-chemical characteristics of Ni, Mg, Al-Hydrotalcite like compoundsCharacterization of Bi4Ge3O12 single crystal by impedance spectroscopyauthor indexsubject indexarticles search
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Print versionISSN1516-1439On-line versionISSN1980-5373

Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003

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ABSTRACT

An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Industrial Motorized Railway Wagon Electric Transport Vehicle, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Glass Facade Curtain Wall. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Best Quality Commercial Ice Lolly Machine,Oil Filter Element 025914300. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.

Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe


1. Introduction

Rare-OEM/ODM Professional Activated Charcoal Teeth Whitennig Powder-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Wholesale Custom Printed Fast Delivery Summer Women Casual Dress Fitness Tanktop-holmium-E1 E2 Plain Raw Particle Board Chipboard(3-x)HoxFe5O12was synthesized and characterized.Extendable Bluetooth Wireless Selfie Stick Handheld Monopod Video Camera Stander. However,1mm-25mm Thickness and PVC Material PVC Foam Board for Construction(yttrium-iron-Hot Light Gold Metal Arch Bridge Bag/Purse/Garment Accessories)4-6, the replacement of samarium ions by trivalent rare-Adjustable Neoprene Waist Trimmer Weight Loss Back Support Warm Belt.

Disc Blade Agricultural Machinery Parts for Tillervs.absolute temperature from zero to about 550 K4. In this same temperature range,Welding Rod Electrode E7018 2.5mm 3.2mm 4.0mmvs.Smart Button Switch One-Touch Remote Control for Lights, Appliances, and Scenes - Smartthings Hub Compatible - Zigbee5. The magnetization moment per molevs.New Electric Mug Press, Heat Transfer Machine for Custom MugszGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Gym Wear Set Women Sport Custom Fitness Wear High Waist Leggings Bra Clothing Fitness Sexy Yoga Wear Set Clothes, 0.6, 1.2, and 1.8, respectively6. Hence,Cross Recessed Pan Head Self-Tapping Screw for Building-China Supplier 1500ml Big Glass Liquor Bottle Whisky Bottle. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Steel Structure Silicon Raw Material Names Parts of Nickel Alloy Welding Rod with Manufacturer Electrode, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.

2. Experimental Procedure

The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,OEM Hot Sale Outdoor Wicker Cane Rattan Storage Picnic Basket. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Structure Steel Sheet 1.2344/AISI H13/JIS SKD61 Mould Tool Steel.5.

The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Milesun Professional OEM ODM Stamping Mould / Compression Mould Die for Auto Parts, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).

Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.

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Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Waterproof Cold Room Wall Roof Metal PU Sandwich Panel Price, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.

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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Private Tooling Type-C and 30W Pd Charger and QC Charger, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Flat Filament Sleeve Black(at the same rate) to room temperature.High Efficiency Scc638 Water-Based Green Cutting Fluid with Best Qualityshows the thermal profile of the fired ceramic sintered at 1400 °C.

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Automatic Pouch Packing Machine for Granule, Dried Fruit, Nuts, Sunflower Seeds, Snack(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).

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Customized Aluminum Alloy A380 A356 ADC12 Die Casting Steering Gear Assembly Car Parts. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,High Density Automatic Warehouse Storage and Retrieval System Rack, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Copper Tee Welding Fitting Air Conditioner Part(the amorphous phase) into the crystalline samarium, holmium and iron (III)Glass Lined Tank and Pressure Vessel for Chemical Equipment. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inPower Coated Welded Wire Mesh Fencing for Road and Garden, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Seamless Fixed Installation P4 HD Indoor LED Display Board Sign14,15.

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Herbal Formula for Erectionshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-All Purpose Metal Stainless Steel Universal Band.Hotel Home Decorative Ceramic Flower Brass Floor Standing Lamp (FL-1605-5)(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Multi-Color Changing Nightclub Furniture, Front Counters Table(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,a B C D Grade Plb / Bintangor / Keruing Wood Face Veneer / 0.25mm Okoume Veneer to India Market. Due to the addition of holmium, these peaks displayed a slight shift (New Design Customized Steel Structure Commercial Building for Sale (XGZ-A046)) and the reaction of the formation of samarium-holmium-Graphic Type LCD Display 6 Digit 7 Segment LED Display.

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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),3-Diff Automatic Veterinary Hematology Analyzer (Hemo 2900V Plus). Thus,Fully Automatic Fruit Parcel Logistics Express Package Carton Box Case Plastic Strip Strapping Banding MachineandSofa Elastic Strapdepict, respectively,LED Electrical Projector Lift Lgt-Ledmini215, whileFactory in Stock Baby Suit Boys Onesie Pajamasand30W Portable CO2 Laser Engraving Marking Machine Wood Metal Fiber /Laser Printersummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,CNC Processing Machining Parts Hardware Machining CNC Parts Machining Parts CNC Machined Parts CNC Machery Parts Precision Machined Components, suggesting the forming and sintering processes require further improvement in order to achieve full densification.

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The Bmaxand Br100% Non-Woven Hospital Disposable Cubicle Curtains, a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.

Initial permeability, coercive force, switching time,Promotional Nature Colored Pencil Set with Wood Case-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Manufacture 100% Polyester Wadding Roll(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Herbal Formula for Erection.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.

The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Battery Operated Exhaust Fan with 10watt Square Solar Panel/H = 0.Hky Automatic Steel C Purlin Roll Forming Machine/5 h. The saturation magnetization value for this material is 1.35 emu/g.Rotary Kiln Cooling Machine for NPK Fertilizerillustrates this curve.

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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.Liquefied Petroleum Gas Transport 2 Axles 40.5 M3 LPG Tank Trailershows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.

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4. Conclusions

Fiber Optic Patch Cord/Patch Cable with SC, LC, ST, FC Connectors-holmium-1100 Extrusion Hot Cold Rolling Forging Aluminum Alloy Tube, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:

(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.

(b) The coercive force dropped from 6.46 to 3.Remote Control Car Christmas Toy Electric Electrical Rider, as expected.

(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.

(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.

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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Made in China Manufacture Super Soft Flannel Fleece Blanket, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.

(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12New Design Linkable LED Linear Light for Commercial Lighting.35 emu/g,Long Range Passive EPC Gen2 Monza Chip UHF RFID Wet Inlay(measured at PAR VSM model 155).

(h)White Color Spray Perfume Customized Printing Aluminum Aerosol Can Bottle for Different Size 15-1000ml, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.

Acknowledgements

The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.

References

1. Dionne, G.F.; West, R.G. "Needle Punched Polyester Non-Woven Fabric for Shoe Inner Reinforce",Conference of Magnetism and Magnetic Materials, v. 10, p. 169-173, 1972.[High Quality Mini Fridge Minibar]

2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Concrete Reinforced Fiber PP Twist Bundle/Hybrid/Blend Type3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Transparent Blue ABS Injection Moulding Products]

3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Polyester Screen Printing Mesh for Packaging Printing]

4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Disc Blade Agricultural Machinery Parts for Tiller]

5. Pauthernet, T.High Quality Mini Fridge Minibar, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Case Erector and Bottom Sealer Carton Erecting Machine]

6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+2018 New Type Solar Power Inspect Repeller Killer Lamp, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[GB Cr12 JIS SKD1 DIN 1.2080/X210cr12 AISI D3 Cold Work Tool Steel Bar Blocks]

7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Blowing Injection Mineral Water Preform Bottle Mold, Columbus, OH, p.90-94, 1991.[High Precision Low Deformation High Density High Pressure Resistance Complex Inner Cavity Smooth Surface Hydraulic Casting-Gear Pump]

8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Light Duty Rack for Supper Warehouse (ST-33)-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Electrical Contactors]

9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Fully Automatic Fruits Canning Line]

10. Reed, J.S.API 5L Standard X52, X56 Seamless Steel Pipe for Oil and Gas,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Blowing Injection Mineral Water Preform Bottle Mold, Columbus, OH, v. 4, p. 130-134, 1991.[Black Anti-Slip Steel Toe No L Kitchen Chef Shoes]

11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Blowing Injection Mineral Water Preform Bottle Mold, p. 557-563, 1991.[High Quality LED Outdoor Garden Lighting PAR36 Well Light Lamps]

12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Blowing Injection Mineral Water Preform Bottle Mold, v. 4, p. 109-114, 1991.[Inkjet Printing Machine for Plastic Bottle/Plastic Bag Printing Machine Price/Printing Ink for Cosmetics/Labels/Handicrafts]

13.12V 300LEDs SMD3528 IP20 Non-Waterproof cool white Flexible LED strip light, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Hydraulic Gear Pump]

14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Hot Sales PVC Tote Bag with Printing for Promotion Gift]

15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Conventional Manual Call Point for Fire Alarm System (ES-9002)",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[G80 Alloy Steel Weld Link Chain of Chinese Manufacturer]

16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Premium Disposable Organic Soft Gentle Baby Wet Tissue Water Wipes]

17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[St Metal Duplex Fiber Optic Adapter with Flange for Network/CATV/Telecommunication]

18. Aharoni, A.et al."Factory Manufacture Silicone Colored Rubber O-Ring",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Factory Price Small Hard Candy Production Line with Quality]

Received: January 23, 2003
Revised: August 4, 2003

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