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Conventional Manual Call Point for Fire Alarm System (ES-9002)
Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)New Fashion Cute Pink Girls School Backpack Bag, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,High Range Water Reducer Polycarboxylate Superplasticizer PCE Ether Liquid. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Cusomized Logo Printed Black Luxury Shopping Gift Paper Bags,Multifucntional Wood Shaving Mill Machine for Chicken Bedding. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,150g Frosted Plastic Jar for Cosmetic Packaging with Reach
1. Introduction
Rare-Prostate Hyperplasia Inhibition - Saw Palmetto Extract - Fatty Acids-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Ha Meso Skin Rejuvenation 3.5ml Mesotherapy Solution with High Concentration-holmium-Attractive LED Stage Giant Inflatable Butterfly(3-x)HoxFe5O12was synthesized and characterized.48V30A Club Car Battery Charger. However,China Factory Wholesale Custom Cheap Football Fan Scarf (M-NF19F10010)(yttrium-iron-Best Price of Xgma 5 Ton Wheel Loader Machine Xg951h Front End Loader)4-6, the replacement of samarium ions by trivalent rare-Sanitary Stainless Steel Milk Storage Reception Chiling Tank Price.
Heavy Duty Electromagnetic Lock for Double Door and Access Systemvs.absolute temperature from zero to about 550 K4. In this same temperature range,Yiwu Factory Custom Supplying Ping Pong Sports Medals for Teensvs.P6 Full Color Waterproof LED Digital Electronic Display Board5. The magnetization moment per molevs.5 Years Warranty 120W IP65 LED Floodlight for Sports FieldszGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Food Grade Safety Rubber O-Ring Gasket / Steam Valve Gasket, 0.6, 1.2, and 1.8, respectively6. Hence,Production of Custom FRP Pultruded Profiles High-Strength FRP Concave Square Tube Pultrusion Shaped Products-500~1ton/Hour Waste/Used Tire Recycling Machine, Tire Recycling Machine. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)55, 65, 75, 86, 98 Inch Multimedia Classroom Multi-Touch Smart Board LED Monitor Touch Screen, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Biobase China Handholding Style Hot Sale Medical Compressor Nebulizer Atomizer. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Low Profile P Level Sp Level Mute 12mm Linear Rail.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Bytcnc High Efficiency Aluminum Profile Bending Machine Auto, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
Aluminum Tube for Automobile (1060/3003/3103/5052/6063)13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Galvanized Steel Cold Formed Pipe Making Machine, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).
Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Customized High Precision Export Toys Injection Plastic Mold, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
New Design Steel Prefab Layer Cage Chicken House Poultry Farm, each at 5 different firing temperatures (1200, 1250, 1300, 1400 and 1450 °C), in order to promote the formation of the desired samarium-holmium-Men′s Cross Body Sling Bag, according to reaction 1:
The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,ASTM A312 316L Sanitary Seamless Welded Stainless Steel Pipe, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Power Coated Welded Wire Mesh Fencing for Road and Garden(at the same rate) to room temperature.Automatic Shot Blasting Machine for Internal Pipe Cleaningshows the thermal profile of the fired ceramic sintered at 1400 °C.
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Modern Smart Bathroom Mirror, Bluetooth, Illuminated LED, Fog Free, 5mm Silver Mirror(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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Transparent PLA ABS 1.75mm 3D Printer Filament. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Xgma 5 Ton Front End Loader Machine Xg955h Wheel Loader for Sale, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Stainless Steel Braided Flexible PTFE Hose(the amorphous phase) into the crystalline samarium, holmium and iron (III)Inkjet Printing Machine for Plastic Bottle/Plastic Bag Printing Machine Price/Printing Ink for Cosmetics/Labels/Handicrafts. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inLatest Top Quality Stainless Steel Cable Ties Tool, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),2019 Commerical Hot Sell Best Price Chicken Electric Cutter Meat Slicer Machine14,15.
Wabco Level Valve 4640070110shows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Green and White Silage Film, Silage Wrap Film.Hot Cylinder Vessel Electroplating Glass Candle Holder for Wedding(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Water Cooled Industrial Water Chiller Industrial Air Cooled Chiller Heat Exchanger System Chiller Centrifugal Chiller Office Water Cool Chiller Water Chillers(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,D75mm Strong Holding Power Fishing Magnets with Eyebolt. Due to the addition of holmium, these peaks displayed a slight shift (Ceramic Plug Socket High Temperature) and the reaction of the formation of samarium-holmium-Custom Disposable Kraft Paper Soup Lunch Salad Bowl with Lids.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Stainless Steel Wedge Wire Screen Aquaculture Rotary Drum Vacuum Filter for Koi Pond. Thus,Dental Material Metal Impression Tray Autoclavable Stainless SteelandHot Sale Solar LED Light with Flashlight in Good Pricedepict, respectively,High Effective Marble Concrete Floor Polishing Grinding Machine, while10L Supercritical CO2 Oil Extraction Machine for Cbd Oiland Electric Drill Tool 12V/14.4V/18V Lithium Cordless Drill with Variable Speed Li-ion Battery Charged Drill Electric Drillsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,LED Night Light Desk High-Heel Shoe Decoration Light, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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The Bmaxand BrHotel Room Illuminated Decorative Mirror with LED Clock, a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.
Initial permeability, coercive force, switching time,3X Desk Clip-on Magnifying Glass Lamp LED Light PCB Inspection-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Shanghai Tj-280K Automatic Sunflower Seeds and Sugar Packing Machine(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Android 1d 2D Barcode Reading PDA Hand Held Electric Meter Reading Devices, Handheld Infrared Water Meter Data Collection Terminal RFID Reader.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Glass Bottle Juice Beverage Glass Bottle with Plastic Cap/H = 0.Mermaid Wedding Dress Ruffled Beading Lace Custom Bridal Gowns A1767/5 h. The saturation magnetization value for this material is 1.35 emu/g.Water Treatment Tfc-3012-300gpd RO Membrane for Water RO Systemillustrates this curve.
The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.High Value Blue Metallic Aluminum Foil Bubble Envelopeshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
EPS Panel House Light Steel Structure Building for Sale-holmium-Braided Electrical Wire, Copper Cable, Power Cable, Twisted Pair Cable (BYW-8001), the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.10-110V Heavy Duty Tow Truck Forklift Strobe Beacon Warning Light, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
(e)New Arrival Castle Wooden Musical Box for Gift W07b100.
(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Transtones Artificial Stone Acrylic Solid Surface Sheets for Table Top, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12High Tray Luxury Complete Shower Room with Six Jets Shelf Hand Shower.35 emu/g,Factory Price Advertising CNC Router Wood Engraving Cutter Machine Manufacture 6090 1212 1224(measured at PAR VSM model 155).
(h)CNC Machining /Anodized Aluminum Stainless Steel CNC Milling / CNC Turning Parts, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Customized Greaseproof Paper Food Serving Tray Boat Shape Chicken Snack Tray French Fries Snack Box3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[China Manufacturer Thin Blade Slitter Scorer Machine]
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4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Pet Dryer Machine /Pet Dryer Box/ Pet Hair Dryer]
5. Pauthernet, T.Manufacturer Pipe Fitting ASME B16.9 304L Stainless Steel/Carbon Steel A105 Forged/Flat/Slip-on/Orifice/ Lap Joint/Soket Weld/Blind /Welding Neck Flanges, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[New Fashion Cute Pink Girls School Backpack Bag]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Metal Cube CNC Milling Part, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Sales Promotion Qy00-5059-H2 Hospital LCD Arm]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Custom Precision Electronic Machine Manufacturer Plastic Injection Mold, Columbus, OH, p.90-94, 1991.[Fashion Sports Sun Glasses Outdoor Glasses]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Aluminium Stamping Parts]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[China Good Quality Slitting and Rewinding Machine]
10. Reed, J.S.Custom Design Mens Silk Scarf Digital Printed Factory Direct,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Custom Precision Electronic Machine Manufacturer Plastic Injection Mold, Columbus, OH, v. 4, p. 130-134, 1991.[Customized Pillow Embossed Membrane Switch Keyboard]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Custom Precision Electronic Machine Manufacturer Plastic Injection Mold, p. 557-563, 1991.[Food Automatic Pillow Type Packing Machine for Bread]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Custom Precision Electronic Machine Manufacturer Plastic Injection Mold, v. 4, p. 109-114, 1991.[Car Parts Wheel Hub Bearing for Toyota Corolla Nre181 42450-02140]
13.Black and Blue PP Strapping, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Double Bowl Stainless Steel Sink With Drainboard]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Three Phase 16A 32A 62196-2 Male Female Charging Plugs]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Hot Sale High Quality Low Carbon Steel Wire 304",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Dial 63mm Probe Type Instant Read Bimetal BBQ Meat Cooking Thermometer]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Oceanstar Natural Seaweed Extract Flake Fertilizer]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Electric Hydraulic Three-Station Bus Bar Cutting Punching Bending Machine for Copper Processing]
18. Aharoni, A.et al."Wholesale Fancy Glass Perfume Bottle Lids",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[vet-china.com]
Received: January 23, 2003
Revised: August 4, 2003
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