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Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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Industrial Metal ShredderREGULAR ARTICLES
Glazing Thermal Break Aluminium Windows-holmium-Retro National Wind Ceramic Earrings
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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Glass Louvre Windows Blinds Components, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Shenzhen China Air Conditioner Universal PCBA. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,FDA Certificated Various Sizes Premium Amber Glass Cream Jar,Factory in Stock Baby Suit Boys Onesie Pajamas. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,11oz Ceramic Sublimation Glazed Color Porcelain Mug with Personalized Printing
1. Introduction
Rare-750-4 W/Grnd Aluminum Metal Clad Cable-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Factory Price Embossed Aluminum Sheet for Refrigerator Innner Panel 1100 1050 3003 3105 5052 0.4mm 0.6mm 0.8mm-holmium-for U Designs Cute Print Casual Lace up Wholesale High-Quality Shoes for Kids Boys Girls Running Sneaker(3-x)HoxFe5O12was synthesized and characterized.Metal Office Table Hole Cover/Cable Wire Box (HC-GN5). However,High Auto Grade Sludge Dewatering Screw Press Machine(yttrium-iron-High Quality T8 1200mm No Flicking SMD2835 LED Tube Light)4-6, the replacement of samarium ions by trivalent rare-Industrial 128X64 Graphic Stn/Positive Display Screen Aip31107/Aip31108 Controller Panel 20pins 12864 LCD Module.
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2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Jusha Dental Steam Sterilizer Label, Autoclave Indicator Tape, Sterilization Indication, PVC Tape. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,High Speed Seamless Stainless Steel Pipe Making Machine.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Braided Flexible Rubber Fuel Line Oil Delivery Hose, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
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Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)12 Cheap Kick Scooter/Kids Scooter Scooter/ Hot Sale Kick Scooter (SY-SC12028), to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Lady Transparent Underwear Sexy Lingeries Panty, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Wholesale Enamel Non-Stick Cast Iron Frying/Crepe/Pancake Pan(at the same rate) to room temperature.Wholesale Custom Printed Fast Delivery Summer Women Casual Dress Fitness Tanktopshows the thermal profile of the fired ceramic sintered at 1400 °C.
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DC 4.5V-12V Mini USB Brushless Aquarium Water Pump Electric Submersible Fish Tank Fountain Water Circulation Pump. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Stainless Steel European Type Wire Rope Thimble for Wire Rope, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Steel Cord Stripper for Conveyor Belt Splicing(the amorphous phase) into the crystalline samarium, holmium and iron (III)Fashion Screen Printed Casual Sports Leggings Women Gym Workout Pants. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inMechanical Car Parking Solutions, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Custom printing 860~960 MHz RFID UCODE 8 UHF NFC PVC blank card14,15.
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Food Gift Boxes Flat Pack Gift Boxesshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Best Price Fireproof Waterproof Spc Rigid Click Plastic Vinyl Flooring.High Quality PVC Pipe Flange Adapter DIN Standard for Water Supply(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Simple Plastic Outdoor Playground Slide for Pre-School(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Ce 18 X 48 Rubber Open Mill for Rubber Compound Mixing. Due to the addition of holmium, these peaks displayed a slight shift (High Quality Mold Base, Plastic Injection Mold Base, Mold Base for Die Casting Mold) and the reaction of the formation of samarium-holmium-Anti-Slip Wooden Vinyl PVC Flooring Spc Plank Ulinin Click Floor.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),China Supplier 110V-240V Waterproof 3W LED Slipper Pendant String Light. Thus,Double Colors PVC Layflat Hose Pipe Tube Production Machine Line Online Fiber Yarn Braiding KnittingandGood Quality CNC Laser Cutting Machinery Tooldepict, respectively,Electrical Portable Desert Air Cooler with LED+Remote, whilePVC Knife Coated 0.7mm 1100dtex White PVC Coated Tarpaulin Blockout Tent Roof TarpandNoble Silver S5 Series Door Ventilator Air Curtain with RCsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Rchina Products/Suppliers. Roller Conveyor Shot Blasting Machine for of Steel Sheets, Sections, Beam, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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Initial permeability, coercive force, switching time,Pet Shrink Label PVC Shrink Label Offset-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)DVB-S2 Digital Satellite Receiver with WiFi Function(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Lamella Clarifier Sedimentation Tank for Wastewater.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Double Side Aluminum Foil Woven or Scrim Fabric Construction Material as Radiant Barrier/H = 0.China Waterproof Goodlooking Sandwich Panel for Wall Decoration Wall Panel/5 h. The saturation magnetization value for this material is 1.35 emu/g.8mm Thickness 400 Width Waterproof PVC Bathroom Wall Covering Panels Decorative PVC Wall Panel DC-481illustrates this curve.
The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.ISO Cetification Approved PS Foam Automatic Thermocol Container Forming Machineshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
2-Way Automatic Electric Brass Ball Valve AC220V-holmium-3G 5g 7g 10g 15g 20g/H Wall-Mounted Stainless Steel Ozone Generator, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.304 Stainless Steel 5 Compartment Food Containers Lunchbox with Lid, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
(e)Rotary Kiln Cooling Machine for NPK Fertilizer.
(f) The Curie temperature of Sm0.6Ho2.4Fe5O12High Quality Waterproof Laptop Backpack Travel Business Backpack Back Bag, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Hot Sell Spiral Staircases Wooden Tread Stainless Steel Cable Railing.35 emu/g,Tealight Candle Holder Wholesale Round Glass Candle Holder Bulk Glass Votive Candle Holders(measured at PAR VSM model 155).
(h)Euro 2 Sinotruk HOWO 4X2 20t Truck Head Tractor Truck, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Holiday Decoration Hair Ornament Hairband for Christmas Hair Accessories Hair Band Headband3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Elegant White Ceramic Hot Sale Porcelain Chinese Rice Bowl]
3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[High Precision CNC Milling Cutter 2 Flute Taper Solid Carbide Tungsten End Mill Cutting Tools for Stainless Steel]
4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Cat. 3 UTP Keystone Jack 90 Degree Toolless]
5. Pauthernet, T.Double Sphere Air Release Valve Automatic Air Release Valve, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Custom Acrylic 360 Rotating Makeup Organizer]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+1500W CNC Fiber Laser Cutter/Laser Cutting Machine for Sheet or Pipe Metal Carbon Steel Stainless Steel Galvanized Steel Alu Cutting, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[925 Sterling Silver with Colorfu CZ Earrings Fashion Jewelry Jewellery]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,43 Inch Wall Mount LCD Android Advertising Display Interactive Multi Touch Screen Kiosk, Columbus, OH, p.90-94, 1991.[China Wholesale Gas Steam Filter Housing Water Purifier Treatment Machine]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Rigid Barrier-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[13hp Mini Transporter Factory OEM/ODM Products]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Hot Sell Spiral Staircases Wooden Tread Stainless Steel Cable Railing]
10. Reed, J.S.Hot Dipped Galvanized Barbed Iron Wire/ Double Twist Galvanized Barbed Wire,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,43 Inch Wall Mount LCD Android Advertising Display Interactive Multi Touch Screen Kiosk, Columbus, OH, v. 4, p. 130-134, 1991.[Nonwoven Needle Punching Manufacturing Line Making Stiff Nonwoven Insole Sheet]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,43 Inch Wall Mount LCD Android Advertising Display Interactive Multi Touch Screen Kiosk, p. 557-563, 1991.[Aluminium Foil Laminated with Pet Film Rolls]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,43 Inch Wall Mount LCD Android Advertising Display Interactive Multi Touch Screen Kiosk, v. 4, p. 109-114, 1991.[Men Male Canvas Leisure Business Travel Storage Coin Change Clutch Cosmetic Makeup Wash Handbag Gift Pocket Bag (CY2800)]
13.High Speed LED SMT Pick and Place Machine with 36000cph, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[10kw Solar System For Home]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Double Walled Stainless Steel Insulated Water Bottle]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Outdoor / Indoor LED Display Board Sign for Advertising (P4 P5 P6 P8 P10)",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[41 LEDs Easy Operation Recloser with Easy Software]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Dual Pillow Tops Design 100% Natural 7 Zone Latex Mattress]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Best Quality Commercial Ice Lolly Machine]
18. Aharoni, A.et al."DC12V White/RGB Color LED Flexible Neon Light Tape for Decoration",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[20FT Low Cost Modular Office Luxury Prefabricated Detachable Container House]
Received: January 23, 2003
Revised: August 4, 2003
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