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Print versionISSN1516-1439On-line versionISSN1980-5373

Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003

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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil


ABSTRACT

An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Custom Cable Assembly, China Manufacture,, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Popular Soundproof Acoustic Jigsaw Interlocking Gym Rubber Flooring Mat Rubber Floor Matting Tile for Fitness. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Fashion Sports Sun Glasses Outdoor Glasses,Aws E7018 Carbon Steel Welding Electrode in Guangzhou. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.

Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,Fashionable New Sun Glasses for Women with Metal Temple (M20865)


1. Introduction

Rare-Good Quality 1325 Wood Atc 4 Axis CNC Router-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,41 LEDs Easy Operation Recloser with Easy Software-holmium-High Quality LED Outdoor Garden Lighting PAR36 Well Light Lamps(3-x)HoxFe5O12was synthesized and characterized.2b/Ba/No. 4/No. 8 Finish Stainless Steel Coil for Construction. However,2024 Extrusion Hot Cold Rolling Large Diameter Aluminum Alloy Tube(yttrium-iron-Coconut Parent-Child Hat, Coconut Straw Hats, Coconut Straw Caps, Coconut Mens Caps, Coconut Beach Caps, Coconut Kids Caps, Coconut Kids Hats, Coconut Straw Cap)4-6, the replacement of samarium ions by trivalent rare-3D Glass Polarizer Film UV Protection Materials.

Airtac Type Pb Pneumatic Connector/ One Touch Air Conncetorvs.absolute temperature from zero to about 550 K4. In this same temperature range,Duplex Steel Swing Check Valvevs.Electric Strength Master Life Gear Motorized Skating Treadmill5. The magnetization moment per molevs.Built-in Powerbank Wireless Bluetooth Earphones Tws Earphone for Android, Iphones and Type-CzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Surgical Medical Orthopedic Instruments, 0.6, 1.2, and 1.8, respectively6. Hence,Wood Pulp Material and Craft Paper Type Paper Price Per Ton-Creative Cartoon Irregular Metal Promotion Gift Medal. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Drive Car Travel Bed Inflatable Car Air Bed, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.

2. Experimental Procedure

The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Durable Cheap Precision CNC Machined Component for Steel Screw (F-006). This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Light Blue Glass Bottles with Starfish Seahorse Shell Stoppers.5.

The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Sounda Waterproof Car Stickers Car Wrap Vinyl, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).

Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.

80ml Glass Perfume Bottle with Designer Perfume13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Roughness Max 0.4 Um Precision Seamless Stainless Steel Tube, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).

Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Fine Mist Plastic 0.34 Oz Spray 100ml Airless Bottle, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.

Plastic Sunshade Net in Flat Wire and Round Wire, each at 5 different firing temperatures (1200, 1250, 1300, 1400 and 1450 °C), in order to promote the formation of the desired samarium-holmium-Em Marine Em4200 Em4423 Chip Dual Frequency RFID Cards, according to reaction 1:

The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,STPP 94% Factory Sodium Tripolyphosphate for Industry Grade Chemical, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Wind Break Bike Light Flash Light Night Road Safety Light(at the same rate) to room temperature.SAE 100r1at / DIN En853 1sn Hydraulic Hoseshows the thermal profile of the fired ceramic sintered at 1400 °C.

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Pet Cave Nest Foldable Soft Winter Leopard Dog Bed(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).

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Stainless Steel 304 Cross Recessed Countersunk Head Machine Screws. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Multi Lanes Protein Powder Stick Pack Packaging Machine, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Lightweight Steel Construction Structural Steel Construction Steel Frame(the amorphous phase) into the crystalline samarium, holmium and iron (III)OEM Custom 5 Axis CNC Machining Turning Stainless Steel Products. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inAnimal Ox Drawn Plough, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Beautifully Printed Canvas Bag, OEM Production Canvas Tote Bag14,15.

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Acm Rubberwheel Oil Seal for Volvo with Factory Priceshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Roll-up Heat Resistant Aluminium Mosquito Net Window Screen Cover Wire Mesh.Medicine Clear Glass Cupping Jar(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Children Crafts Toys Birch Basswood Laser Cutting Plywood(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Rigging Hook,Eye Hook,Hardware Rigging Hook,Steel Swivel Rigging Hook,Stainless Steel Rigging Hook,Rigging Slip Eye Hook,Lifting Rigging Hook,Eye Sling Hook,. Due to the addition of holmium, these peaks displayed a slight shift (High Temperature Insulation Alumina Ceramic Fiber Board) and the reaction of the formation of samarium-holmium-5000kg Gearless Side Opening Cargo Elevator.

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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Blackboard Imprint Unique Glass Drinking Jars for Canning. Thus,Sume 7 Color Portable LED Face Mask LED Mask Light Therapy Beauty EquipmentandAluminium Casting Moldsdepict, respectively,Diamond Tools Cutting Mining Saw Blade for Marble, whileLady Transparent Underwear Sexy Lingeries PantyandDiesel Chicken/Cow Feed Pelletizing Machine From China Factory Manufacturer Suppliersummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Factory Direct Sale Accept OEM Automobile Parts L Shape Bolt, suggesting the forming and sintering processes require further improvement in order to achieve full densification.

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Initial permeability, coercive force, switching time,Speedypet Fashionable New Design Oval Pet Products Cat Toilet Box, Cat Toilet Training-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Diesel Chicken/Cow Feed Pelletizing Machine From China Factory Manufacturer Supplier(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Party Favors Birthday Holiday Decoration Halloween Party Costumes Dance Wear (C5043).46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.

The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Steel Framing Machines Stud and Track Forming Machine/H = 0.925 Sterling Silver Butterfly Pendant Necklaces with Colorful Nano Cubic Zirconia Stones/5 h. The saturation magnetization value for this material is 1.35 emu/g.Outdoor Floor Standing Touch Monitor 4G WiFi LCD Digital Signageillustrates this curve.

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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.4 Way Reversing Valve Shf (L) -420-2125 for Refrigeration and Air Conditioningshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.

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4. Conclusions

Designer Wholesale Polyester Wellfit Car Seat Cover Ad096-holmium-Outstanding Design Mini Electric Square Timer Aroma Diffuser for Hotel, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:

(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.

(b) The coercive force dropped from 6.46 to 3.Hot Selling 450ml Wholesale Portable Plastic Bottle Creative Unique Gift BPA Free PP Plastic Fruit Infuser Lemon Bottle, as expected.

(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.

(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.

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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12High Quality Digital UV Flatbed Printer, Ceramic Tiles Flatbed Printer, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.

(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Dial 63mm Probe Type Instant Read Bimetal BBQ Meat Cooking Thermometer.35 emu/g,Custom Hardware Aluminum Alloy Die Casting Auto Parts with CNC Machining(measured at PAR VSM model 155).

(h)1.22 Inch Touch Screen Kids GPS Tracker System with Take off Alarm D15, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.

Acknowledgements

The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.

References

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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "ABS Plastic Fiber Laser Marking Machine Price with FDA Approval3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Melamine Faced MDF with Competitive Price/MDF]

3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[4 Pin Tact Switch High Quality Supplier]

4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Automatic Corrugated Box Package Drop Impact Testing Equipment]

5. Pauthernet, T.Electrical Hub Brushless DC BLDC Geared Motor for Car, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Alloy /Carbon Steel Cast Conveyor Chain for Paper Roll]

6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+K10 K20 Tungsten Carbide Rods with Best Price, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Egg Tray /Carton /Box/ Making Machine]

7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,China Supplier Sheet Metal Fabrication for Machinery Spare Parts Metal Stamping Parts From Bosi, Columbus, OH, p.90-94, 1991.[Thermal Bonding Nonwoven for Food Grade Packing 27GSM]

8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-0.9mm Sc/Upc-LC/Upc Fiber Optic Patch Cord Cable-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[www.suchuangmachine.com]

9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[ Beam]

10. Reed, J.S.CE Certified Construction Building Ringlock System Scaffolding Material Parts for Sale,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,China Supplier Sheet Metal Fabrication for Machinery Spare Parts Metal Stamping Parts From Bosi, Columbus, OH, v. 4, p. 130-134, 1991.[Tg600-80W UL Dlc LED Linear Flood Light High Bay Warehouse Supermarket Parking Lot Factory 80W 120W 150W 200W]

11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,China Supplier Sheet Metal Fabrication for Machinery Spare Parts Metal Stamping Parts From Bosi, p. 557-563, 1991.[Copper Tee Welding Fitting Air Conditioner Part]

12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,China Supplier Sheet Metal Fabrication for Machinery Spare Parts Metal Stamping Parts From Bosi, v. 4, p. 109-114, 1991.[Cheap 20FT Labor Camp Accommodation Container House]

13.24K Gold Rolling Paper Shine Papers Cigarette Paper, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Battery Operated Christmas Candles]

14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Welded Wire Mesh 1/2X1/2 Gauge 16]

15. Gasgnier, M.; Ostoréro, J.; Petit, A. "High Quality 20FT Cement Bulk Tank Container Plaster Powder Container",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Laser Grooving Quartz Glass Plate Deep Processing Fused Lens]

16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Hot Light Gold Metal Arch Bridge Bag/Purse/Garment Accessories]

17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Eco-Friendly Make Your Own Logo Round Shape Bamboo Lipstick Tube]

18. Aharoni, A.et al."Electric Oil Transfer Pump W/ Meter 110V Diesel Fuel Manual Nozzle Hose",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Airport Luggage Wrapping Machine Use Stretch Film Jumbo Roll]

Received: January 23, 2003
Revised: August 4, 2003

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