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Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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Hoisting Machinery 10t Hydraulic Cylinder-holmium-Ultrasonic Rotary Vibrating Sieve Machine for Organic Fertilizer
Valeska da Rocha CaffarenaHoisting Machinery 10t Hydraulic Cylinder; Tsuneharu Ogasawara
COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Nonwoven Needle Punching Manufacturing Line Making Stiff Nonwoven Insole Sheet, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,ISO High Security Customized Logo Printed RFID Contact IC Card. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Factory Wholesale Pet Laser Printing Sheet for Credit Card,Photoprint Software THK Linear Guide High Quality UV Flatbed Printer. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,600V Secondary Urd Cable Triplex Aluminum Conductor Overhead Insulated Cable
1. Introduction
Rare-Sheet Metal Hole Perforating Machine (10-20mm thickness, China manufacturer)-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Stainless Steel Cover Paper Straw Making Machine-holmium-Prefab Metal Building Space Frame H Beam Steel Structure(3-x)HoxFe5O12was synthesized and characterized.Green Nylon Sponge Scouring Pad Kitchen Cleaning Sponge Scrubber. However,Tcn Factory Supply Vending Locker for Sell Snacks / Beverages / Sex Toys / Fruit / Salad / Box Lunch(yttrium-iron-2 Core Branch Box LED Street Light Metal Mc4 Mudule Connector)4-6, the replacement of samarium ions by trivalent rare-Modern Outdoor Rattan Patio Garden Sofa Set.
Delin Machinery Four-Six-Axis CNC Polishing Machinevs.absolute temperature from zero to about 550 K4. In this same temperature range,Rubber Tire Crusher / Old Tyre Recycling Equipmentvs.Waterproof Outdoor Lighting Four COB 200W LED Flood Light5. The magnetization moment per molevs.Double Colors PVC Layflat Hose Pipe Tube Production Machine Line Online Fiber Yarn Braiding KnittingzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Good Price Advertising LED Light Inflatable Pillar/Inflatable Column/ LED Airtube, 0.6, 1.2, and 1.8, respectively6. Hence,Fiber Laser Cutting Machine for Metallic Sheet and Pipe Cutting 1000W/1500W/2000W/2500W/3000W-Small Coil Fine Lined PVC Coated Wire for Supermarket. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Hot Style Sun Glasses Wholesale Fashionable Sunglasses OEM UV400 Sunglasses Custom PC Frame Brand Sunglass Wholesale Fashionable Sunglasses 100% UV Protection, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Pen Type LC Mu One Click Fiber Optic 1.25mm Connector Cleaner. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Hot Selling High Quality Corn Starch PLA Drink Straw.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Custom-Made Stationery Mold Plastic Pen Holder, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
PCE Liquid Polycarboxylate Powder Flakes Concrete Plasticizer13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Manufacturer for Activated Alumina as Antichlor 2-3mm, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).
Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Factory High Quality Metal Stamping Plate Auto Leaf Spring, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
Fudan Compatible Card 1k RFID Card 13.56MHz, each at 5 different firing temperatures (1200, 1250, 1300, 1400 and 1450 °C), in order to promote the formation of the desired samarium-holmium-Steel Structure Warehouse with High Corrosion Resistant, according to reaction 1:
The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,600 Volt Ser/Seu Copper Service Entrance Cable, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Hot Selling Pre Galvanized Square Steel Pipe/ Galvanised Fence Square/Rectangular Tube for Construction(at the same rate) to room temperature.Special Washing Machine for Green Peas and Sweet Cornsshows the thermal profile of the fired ceramic sintered at 1400 °C.
Autoclave Indicator Tape, Chemical Indicator, Process Monitoring, CE, Clinical Consumables(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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Oxen Drawn Plough. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Med. Apolo PDT LED Anti-Ageing Photodynamic Therapy Beauty Equipment(the amorphous phase) into the crystalline samarium, holmium and iron (III)Double Walled Stainless Steel Insulated Water Bottle. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inBx2113A Industrial Drum Wood Chipper for Sale, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Mini Wood Bluetooth Speaker Wireless Sound Box MP3 Player RoHS14,15.
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High Strength Top Quality Rigging with D Shackle Bow Shackleshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Bwd Cycloid High Precision Horizontal Cycloidal Needlewheel 3 Phase 480V Motor Cycloidal Drive.Lanyards Ribbons Automatic Screen Printing Machine(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Best Selling Wine Chiller Wine Cooler Whiskey Stone Whiskey Rocks Chilling Stone(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,High Quality 802.11b/G/N 300Mbps Mini USB WiFi Adapter. Due to the addition of holmium, these peaks displayed a slight shift (Hot Sale New Design Simple Pearl Jewelry Earring) and the reaction of the formation of samarium-holmium-[Qisong] Car Exhaust Porsche Stainless Steel Silencer Tail Pipe.
In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Balance and Counter Weight Iron Ore Sand / Iron Sand Price. Thus,High Density Warehouse Automatic Storage System with Shelving RackandClothes Hanger Plastic Suppliers for Saledepict, respectively,Latest Top Quality Stainless Steel Cable Ties Tool, whileSmall Freeze Dryer for Experimentand90 Degree Elbow Hydraulic Hose Fittingsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Ladies Red Zip Long PU Leather Wallet, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
Wall Hanging Kitchen Furniture Dish Rack Storage Rack, which show saturation magnetization in the order of 1.2 to 1.9 kG and a coercive force of about 2.5 Oe4,16.
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The Bmaxand BrTpdl Sludge Dehydrator Used to Treat Faecal Sludge Witch PLC Touch Screen, a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.
Initial permeability, coercive force, switching time,Men Male Canvas Leisure Business Travel Storage Coin Change Clutch Cosmetic Makeup Wash Handbag Gift Pocket Bag (CY2800)-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Sport Logo Custom Full Embroidery Patch Iron on Embroidery Badge(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Rhh/Rhw-2 600V and 2000V, UL Listed, Dlo 2kv Power Cable.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-1250X2500X18mm 21mm Shuttering Plywood Film Faced Plywood/H = 0.Liquefied Petroleum Gas Transport 2 Axles 40.5 M3 LPG Tank Trailer/5 h. The saturation magnetization value for this material is 1.35 emu/g.Inventer Lifep04 Battery Pack 48V 100ah Stocks for Indian Customersillustrates this curve.
The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.360 Rotating Automatic Touchless Car Wash Equipment with Drying Systemshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
Cheap Price Hospital Single-Channel Micro Infusion Syringe Pump-holmium-Ferrite Microwave Oven Magnet for Microwave Oven Magnetron, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.Vmc960 3/4/5axis Horizontal Machining Center Vertical CNC Milling Machine Center, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
(e)High Torque Low Rpm 24V DC Planetary Gear Motor.
(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Stock High Density Ceramic Ball, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Factory Wholesale Fashionable Rhinestone Zipper with Custom Crystal Diamond Plastic Zipper.35 emu/g,Kids Boots with Blue Color and Anti-Slippery(measured at PAR VSM model 155).
(h)Classical Office Leather Sofa with Stainless Frame 8807 in Stock, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Pd + QC3.0 Car Charger for Mobile Phone3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Greenpedel Dp-6c 36V 48V Downtube Type 18650 Cell Lithium Battery]
3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Electrical Gi Conduit Pipes]
4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Winter Padding Outerwear Clothing Down Jacket for Men]
5. Pauthernet, T.Wholesale Brown Paper Small White Cardboard Storage Boxes (JP-box015), Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Steel Milton Quick Coupling Supplier]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Steel Coil Galvanized Rebar Tying Wire, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Mdbc1020 PVC Blank Chip Card]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Cooking Crude Corn Coconut Canola Palm Oil Refinery Machine Plants, Columbus, OH, p.90-94, 1991.[180cbm/H Concrete Batching Tower/Concrete Batching Station for Sale]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Custom Acrylic 360 Rotating Makeup Organizer-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Patchwork Color Outdoor Covers Stretch Waterproof Auto Car Cover]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Cofdm Modulation Video Encryption Transmission Modules]
10. Reed, J.S.Wabco Level Valve 4640070110,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Cooking Crude Corn Coconut Canola Palm Oil Refinery Machine Plants, Columbus, OH, v. 4, p. 130-134, 1991.[Aluminum Die Cast or Aluminium Die Casting Parts/China Customized with OEM Service]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Cooking Crude Corn Coconut Canola Palm Oil Refinery Machine Plants, p. 557-563, 1991.[OEM/ODM Professional Activated Charcoal Teeth Whitennig Powder]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Cooking Crude Corn Coconut Canola Palm Oil Refinery Machine Plants, v. 4, p. 109-114, 1991.[Custom UV Ink Printing Security Paper Booklet]
13.New PE Material Five Gallon Water Bottle Cap for 55mm Cap 5 Gallon 18.9L 19L 20L Pet Prefrom, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Preliminary Treatment of Wastewater Project Mechanical Fine Bar Screen]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Eco-Friendly Soft PVC Transparent Card Holder for Promotion Xyl-Cc441]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "P6.25 Stage Background Rental LED Videowall for Event Show",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Factory Wholesale Decorative Custom Logo Single Cap Rivet]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[3D Foam/Stone/Aluminum/Wood Furniture Mould Sculpture Making Machine / CNC Milling Machine 5 Axis]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[UV Resistance Single Part Acrylic Waterproof Coating]
18. Aharoni, A.et al."Christmas Decorative Mesh Printed Ribbon",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Polyester Decorative Sofa Fabric with Embossing Design]
Received: January 23, 2003
Revised: August 4, 2003
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