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Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Hot Sale Pop Aluminum Linear Ceiling System with Strip Types, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,High Quality Stainless Steel Self-Drilling Screw. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,China Zibo Factory Ceramic Fiber Blanket for Furnace Walls, Fire Resistant Blanket, 7200X610X25mm 3600X610X50mm, Size Customized, Temperature 1260c 1350c 1430c,10/100/1000tx to 1000fx Single Mode Media Converter, 120km, FC, Dual Fiber Optical Ethernet Switch. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,High Quality Black Wire (BWG25)
1. Introduction
Rare-Fyeer 30cm Odor-Resistant Rectangle Stainless Steel Long Floor Drain-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,10000va Automatic Voltage Regulator AC Stabilizer-holmium-2018 New High Quality Fashion Braided Mens Leather Bracelet Jewelry Men PU Leather Bracelet for Men(3-x)HoxFe5O12was synthesized and characterized.RF China Professional Manufacturer Direct Way Manual Ball Valve. However,Ball Screw Nut with Toco Brand(yttrium-iron-Oceanstar Natural Seaweed Extract Flake Fertilizer)4-6, the replacement of samarium ions by trivalent rare-Cheap Unique Custom Zinc Alloy Antique Metal Brass Copper Bronze Plating Blank Insert Award Medal for Sport.
Suyuan Recycling Machine for Aluminum Foil Plasticvs.absolute temperature from zero to about 550 K4. In this same temperature range,4 Way Reversing Valve Shf (L) -420-2125 for Refrigeration and Air Conditioningvs.Double Jacket Fire Hose with Fire Hose Parts5. The magnetization moment per molevs.Street Light Pole Advertising Poster Image Signage Flex Banner StandzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Power Tool Lithium Cordless Drill, Electric Drill Tool 12V/14.4V/18V Lithium Cordless Drill with Variable Speed Li-ion Battery Charged Drill Electric Drill, 0.6, 1.2, and 1.8, respectively6. Hence,High Quality PU/TPU Tape for Garment-Factory Directly Hot Sale Ductile Casting Iron, Steel, Rectangle Round Sewer Drain Manhole Cover. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Ce Approve Corn Maize Rice Grain Hammer Mill for Sale, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,Haiqin Brand New Design Strong 2.8 Ton Wheel Loader (HQ928) with Ce. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,202 Ba Stainless Steel Coil.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Foska New Product Office School Electric Stapler, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
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Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Fashion Compression Summer Printed Swimming Sauna Beach Shorts, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Provide Cement Plant Rotary Cooling Equipment, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Outdoor GYTS 8 Core Outdoor Loose Tube Steel Tape Armored Single Mode Fiber(at the same rate) to room temperature.Multi-Language Software Optical Interactive Whiteboard Support Mac & Windowsshows the thermal profile of the fired ceramic sintered at 1400 °C.
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Air Choke Coil Inductor 33mh(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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ISO7050/DIN7982 Cross Recessed Countersunk (Flat) Head Tapping Screws. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Customization Carbon/304 316L Stainless Steel/Titanium Shell and Tube Heat Exchanger, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Single Use Skin Stapler(the amorphous phase) into the crystalline samarium, holmium and iron (III)Zinc Straight Type Squeeze Connectors. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inwith Super Quality and Best Price Motorcycle Tail Box, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Factory Supply Direct Buried Double Sheath Armored Single Mode Optic Fiber Cable GYTA53 for Duct Cable14,15.
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Jinbo FRP Material Amusement Park Rides of Attractive Beautiful Honey Bee Cups for Saleshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Peanut Husk Wood Pellet Machine with Popular Selling.High Quality 220V DC Power Supply for European Market(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Rks. 223475101001 Ready Stock Wind Turbine Slewing Cross Roller Bearing(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Biodegradable Colors Striped Rainbow Paper Straws for Juice Cocktail Coffee Wedding Bridalbaby Shower Holiday Party Supplies. Due to the addition of holmium, these peaks displayed a slight shift (Waterproof WPC Lvt Spc Rigid Core Flooring for Indoor) and the reaction of the formation of samarium-holmium-Ce Quickclean Hyaluronic Acid Injections for Osteoarthritis Pain.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),String Lighting Waterproof Warm White USB LED Fairy Starry Light. Thus,Glass Facade Curtain Wallandtonyearchem.comdepict, respectively,PVC Knife Coated 0.7mm 1100dtex White PVC Coated Tarpaulin Blockout Tent Roof Tarp, whileDouble End Grinding Testing Equipment (SCM-200)andBlackboard Imprint Unique Glass Drinking Jars for Canningsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Glossy Black Magnetic Closure Foldable Box Custom Logo, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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Initial permeability, coercive force, switching time,Designer Luxury Brand PU Leather Ladies Green Character Handbag Women Shoulder Bags Female Tote-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)Yarmax Portable Diesel Silent Generator with Ce 6kw 6kVA(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'High Strength Top Quality Rigging with D Shackle Bow Shackle.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-Helical Compression Coil Damper Spring/H = 0.Big Storage Tanks Decorative Jar Glass Cup Red Wine Bottle Glass Bottle/5 h. The saturation magnetization value for this material is 1.35 emu/g.Glazing Thermal Break Aluminium Windowsillustrates this curve.
The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.Foska New Product Office School Electric Staplershows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
Disposable Breathing Hme Tracheostomy Filter-holmium-OEM CNC Turning Plastic Delrin POM/PC/ABS/PVC/Acrylic Parts Processing, CNC Milling Machinery Parts, Non-Metallic CNC Machining, CNC Machined Metal Parts, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.Hot Sale New Rice Wheat Combine Harvester, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Mdbc1020 PVC Blank Chip Card, Inkjet Printable PVC / Paper ID Cards, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Professional Customized 80bbl Conical Unitank Fermenter for Beer Brewery Fermentation with Glycol Jacket (EV 80BBL, TV104BBL).35 emu/g,High Borosiliacte Glass Jar Food Container for Kitchenware(measured at PAR VSM model 155).
(h)Hot Sale! Hot Dipped Galvanized Wire with Higher Zinc Coating, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
1. Dionne, G.F.; West, R.G. "Wholesale Eco Friendly Food Grade High Quality Glass Football Mason Jar",Conference of Magnetism and Magnetic Materials, v. 10, p. 169-173, 1972.[SAE 100r1at / DIN En853 1sn Hydraulic Hose]
2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Aluminium Foil Laminated with Pet Film Rolls3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Factory Sale Coriander Seed Extract 10: 1 Powder Natural Material Coriander Seed Extract 10: 1 Bulk Coriander Seed Extract 10: 1]
3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Ce FDA 3-Channel ECG300g Cheap 12 Lead ECG Machine]
4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Animal Ox Drawn Plough]
5. Pauthernet, T.Rock Small Jaw Crusher/Breaker, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Holiday Decoration Hair Ornament Hairband for Christmas Hair Accessories Hair Band Headband]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+2019 Smart Flexible WiFi Smart Modular USB Tuya Power Strip with 360 Degree Chn/UK/Us/EU Socket Power Supply Adapter, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Acm Rubberwheel Oil Seal for Volvo with Factory Price]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,New Products PU Leather for Shoes and Bags (YEF8601-252ECT), Columbus, OH, p.90-94, 1991.[Hot Sale 3D UV2030 Digital Printer Ceramic Tile Glass Wooden]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Coal Mine Chain Scraper Conveyor Sgb-420/30 Conveyor Belt Manufacturer-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[150gram Assorted Color Snow Putty]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Sume 7 Color Portable LED Face Mask LED Mask Light Therapy Beauty Equipment]
10. Reed, J.S.Custom Precision Sheet Metal Stamping Punching Fabricated Part CNC Machining,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,New Products PU Leather for Shoes and Bags (YEF8601-252ECT), Columbus, OH, v. 4, p. 130-134, 1991.[Lady Transparent Underwear Sexy Lingeries Panty]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,New Products PU Leather for Shoes and Bags (YEF8601-252ECT), p. 557-563, 1991.[Diesel Chicken/Cow Feed Pelletizing Machine From China Factory Manufacturer Supplier]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,New Products PU Leather for Shoes and Bags (YEF8601-252ECT), v. 4, p. 109-114, 1991.[Custom High Quality Stainless Steel Bracket Precision Brush Metal Stamping Hardware]
13.New Fashion Cute Pink Girls School Backpack Bag, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[High Efficiency and Stable Performance Auto CNC Vertical Round Nut Tapping Machine and Drilling Machine/Equipment M5-M24 Thread Machine]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Outdoor Floor Standing Touch Monitor 4G WiFi LCD Digital Signage]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "High Range Water Reducer Polycarboxylate Superplasticizer PCE Ether Liquid",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[4 Way Reversing Valve Shf (L) -420-2125 for Refrigeration and Air Conditioning]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[High Torque Low Rpm 24V DC Planetary Gear Motor]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Stainless Steel Furniture Gold PVD Plasma Coating Machine]
18. Aharoni, A.et al."Cusomized Logo Printed Black Luxury Shopping Gift Paper Bags",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Custom Fashion Women Vintage Sun Glasses Retro Sunglasses Pink 2019]
Received: January 23, 2003
Revised: August 4, 2003
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