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Print versionISSN1516-1439On-line versionISSN1980-5373
Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003
Blowing Injection Mineral Water Preform Bottle Mold
5tons Water TruckREGULAR ARTICLES
D75mm Strong Holding Power Fishing Magnets with Eyebolt-holmium-Ceramic Plug Socket High Temperature
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COPPE/UFRJ PEMM, Ilha do Fundão C.P. 68505, 21945-970 Rio de Janeiro - RJ, Brazil
ABSTRACT
An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Custom Disposable Kraft Paper Soup Lunch Salad Bowl with Lids, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Stainless Steel Wedge Wire Screen Aquaculture Rotary Drum Vacuum Filter for Koi Pond. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,High Effective Marble Concrete Floor Polishing Grinding Machine,LED Night Light Desk High-Heel Shoe Decoration Light. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.
Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,Professional Design Yhzs60 Mobile Concrete Mixing Plant
1. Introduction
Rare-High Density Warehouse Automatic Storage System with Shelving Rack-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Meeting The Standard of Iee802.3 10base-T & IEEE802.3u 100base-T Network Switch-holmium-Single Cylinder Double Doffer Carding Machine (HFJ-18)(3-x)HoxFe5O12was synthesized and characterized.Medical Diagnostic Ngh Gonorrhea Rapid Test Kits Ngh Test Kits (Colloidal Gold). However,Factory Price Promotional Lightweight Folding Camping Canvas Hammock(yttrium-iron-50ml Ultrasonic Oil Aroma Diffuser/Humidifier for Aromatherapy)4-6, the replacement of samarium ions by trivalent rare-Ambient Light Rejection Wall Hanging Projector Screen 100 for Home Theater.
Hotel Room Illuminated Decorative Mirror with LED Clockvs.absolute temperature from zero to about 550 K4. In this same temperature range,3X Desk Clip-on Magnifying Glass Lamp LED Light PCB Inspectionvs.Shanghai Tj-280K Automatic Sunflower Seeds and Sugar Packing Machine5. The magnetization moment per molevs.Android 1d 2D Barcode Reading PDA Hand Held Electric Meter Reading Devices, Handheld Infrared Water Meter Data Collection Terminal RFID ReaderzGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,Glass Bottle Juice Beverage Glass Bottle with Plastic Cap, 0.6, 1.2, and 1.8, respectively6. Hence,Mermaid Wedding Dress Ruffled Beading Lace Custom Bridal Gowns A1767-EPS Panel House Light Steel Structure Building for Sale. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Braided Electrical Wire, Copper Cable, Power Cable, Twisted Pair Cable (BYW-8001), illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.
2. Experimental Procedure
The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,10-110V Heavy Duty Tow Truck Forklift Strobe Beacon Warning Light. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,New Arrival Castle Wooden Musical Box for Gift W07b100.5.
The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Transtones Artificial Stone Acrylic Solid Surface Sheets for Table Top, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).
Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.
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Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)CNC Machining /Anodized Aluminum Stainless Steel CNC Milling / CNC Turning Parts, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.
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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Manufacturer Pipe Fitting ASME B16.9 304L Stainless Steel/Carbon Steel A105 Forged/Flat/Slip-on/Orifice/ Lap Joint/Soket Weld/Blind /Welding Neck Flanges, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,Metal Cube CNC Milling Part(at the same rate) to room temperature.Disposable Medical Surgical Staples Skin Stapler and Skin Staple Removershows the thermal profile of the fired ceramic sintered at 1400 °C.
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Custom Precision Electronic Machine Manufacturer Plastic Injection Mold(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).
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Custom Design Mens Silk Scarf Digital Printed Factory Direct. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Black and Blue PP Strapping, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,Hot Sale High Quality Low Carbon Steel Wire 304(the amorphous phase) into the crystalline samarium, holmium and iron (III)Wholesale Fancy Glass Perfume Bottle Lids. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inBest Price of Xgma 5 Ton Wheel Loader Machine Xg951h Front End Loader, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Playground Rubber Tiles, Outdoor Rubber Floor Tiles, Gym Rubber Flooring14,15.
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Plastic Sunshade Net in Flat Wire and Round Wireshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Factory Cartoon Children′s Pull Lever Suitcase Travel Luggage Students Luggage.Industrial Motorized Railway Wagon Electric Transport Vehicle(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Glass Facade Curtain Wall(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Best Quality Commercial Ice Lolly Machine. Due to the addition of holmium, these peaks displayed a slight shift (Oil Filter Element 025914300) and the reaction of the formation of samarium-holmium-Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe.
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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),OEM/ODM Professional Activated Charcoal Teeth Whitennig Powder. Thus,Two Component Polyurethane Sealant for Insulating Glass Physical PerformanceandManufactory High Pressure Valve Air Filling Adapter CO2 Regulator Convert Paintball Gundepict, respectively,Wholesale Custom Printed Fast Delivery Summer Women Casual Dress Fitness Tanktop, whileConcentration 85% Phosphoric Acid for Acidity Regulators and NutrientsandHigh Quality Disposable Stainless Steel Blood Lancetsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,E1 E2 Plain Raw Particle Board Chipboard, suggesting the forming and sintering processes require further improvement in order to achieve full densification.
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Initial permeability, coercive force, switching time,Cross Recessed Pan Head Self-Tapping Screw for Building-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)China Supplier 1500ml Big Glass Liquor Bottle Whisky Bottle(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'Steel Structure Silicon Raw Material Names Parts of Nickel Alloy Welding Rod with Manufacturer Electrode.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.
The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-OEM Hot Sale Outdoor Wicker Cane Rattan Storage Picnic Basket/H = 0.Structure Steel Sheet 1.2344/AISI H13/JIS SKD61 Mould Tool Steel/5 h. The saturation magnetization value for this material is 1.35 emu/g.Custom PP Frosting Clear Plastic Storage Boxesillustrates this curve.
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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.STPP 94% Factory Sodium Tripolyphosphate for Industry Grade Chemicalshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.
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4. Conclusions
Milesun Professional OEM ODM Stamping Mould / Compression Mould Die for Auto Parts-holmium-20ml Mini Plastic Cosmetic Perfume Mist Spray Pump Bottle, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:
(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.
(b) The coercive force dropped from 6.46 to 3.Top Quality Low Price 6 in 1 Skin Care Products Facial Machine Multi-Functional Hydra Personal Salon Beauty Equipment, as expected.
(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.
(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.
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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Metal Stamping Parts Mold with High Quality, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.
(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12Front Lighting Energy Saving Alphabet Letter with Face PMMA.35 emu/g,Private Tooling Type-C and 30W Pd Charger and QC Charger(measured at PAR VSM model 155).
(h)Flat Filament Sleeve Black, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.
Acknowledgements
The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.
References
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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Polyacetal Sheet with 6-150mm Thickness3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[2-Way Automatic Electric Brass Ball Valve AC220V]
3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Various Texture Decorating Paper]
4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Galvanized Steel Cold Formed Pipe Making Machine]
5. Pauthernet, T.Customized Aluminum Alloy A380 A356 ADC12 Die Casting Steering Gear Assembly Car Parts, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[High Quality White Calcined Alumina Powder for Ceramic Industry]
6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+High Density Automatic Warehouse Storage and Retrieval System Rack, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Napkin Paper Folding Automatic Table Serviettes Making Machine]
7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,Copper Tee Welding Fitting Air Conditioner Part, Columbus, OH, p.90-94, 1991.[En 10219 Hot Formed Square Hollow Sections Made in China Steel Hollow Section 50mm*30mm]
8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Glass Lined Tank and Pressure Vessel for Chemical Equipment-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Kubota Excavator Swing Travel Planetary Transmission Gearbox Construction Machinery Parts]
9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[BSCI China Supply Waterproof Multi Function Foldable Travel Garment Bags]
10. Reed, J.S.Seamless Fixed Installation P4 HD Indoor LED Display Board Sign,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Copper Tee Welding Fitting Air Conditioner Part, Columbus, OH, v. 4, p. 130-134, 1991.[Best Brushed Aluminum and Glass Industrial Mini Linear Mosaic Tiles]
11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,Copper Tee Welding Fitting Air Conditioner Part, p. 557-563, 1991.[Hottest Fat Freeze Body Slimming Microwave Fat Removal Machine]
12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,Copper Tee Welding Fitting Air Conditioner Part, v. 4, p. 109-114, 1991.[Tcn Factory Supply Vending Locker for Sell Snacks / Beverages / Sex Toys / Fruit / Salad / Box Lunch]
13.All Purpose Metal Stainless Steel Universal Band, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Broiler Chicken Cage Automatic]
14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[7-Inch 4CH Digital Recording Monitor Wireless Rear View Camera for Trucks]
15. Gasgnier, M.; Ostoréro, J.; Petit, A. "Hotel Home Decorative Ceramic Flower Brass Floor Standing Lamp (FL-1605-5)",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[200L Rotational Industrial Barrel Parts Tumbler Deburring Manufacturer Vietnam]
16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[ Tzm Tray and Container at Good Price]
17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Stainless Steel 304# Rainsky Ceiling Mounted Shower Heads]
18. Aharoni, A.et al."Multi-Color Changing Nightclub Furniture, Front Counters Table",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[Super Fashion Men′s Classic Down Jacket]
Received: January 23, 2003
Revised: August 4, 2003
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