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Print versionISSN1516-1439On-line versionISSN1980-5373

Mat. Res. vol.6 no.4 São Carlos Oct./Dec. 2003

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ABSTRACT

An investigation was made into the synthesis and magnetic properties of Sm(3-x)HoxFe5O12(samarium-holmium-iron)Customized Greaseproof Paper Food Serving Tray Boat Shape Chicken Snack Tray French Fries Snack Box, as yet absent from the literature. The material in question was synthesized by co-precipitation, starting from hydrated chlorides of rare-earth elements and ferrous sulfate, and the mixed hydroxide co-precipitate was calcined at 1000 °C. Using PVA as a binder, rectangular cross section-shaped compacts were produced by means of steel-die pressing,Manufacturer Pipe Fitting ASME B16.9 304L Stainless Steel/Carbon Steel A105 Forged/Flat/Slip-on/Orifice/ Lap Joint/Soket Weld/Blind /Welding Neck Flanges. The main conclusions of this study were that the coercive force decreases as the sintering temperature increases,Metal Cube CNC Milling Part,Custom Precision Electronic Machine Manufacturer Plastic Injection Mold. An in-depth investigation will be necessary to determine the correlation between microstructure/magnetic properties and ceramic processing variables.

Keywords:ceramics, chemical synthesis, electron microscopy, magnetic properties,Cheap Custom Promotion Simple Laminated Recycled Plastic Polypropylene Foldable Eco-Friendly Recyclable Garment Carrier Grocery Tote Non-Woven Shopping Bag


1. Introduction

Rare-Custom Design Mens Silk Scarf Digital Printed Factory Direct-structured ferrites, R3Fe5O12(where R is yttrium or a rare-earth cation), continue attracting a great deal of attention1,2for both microwave devices and magnetic recording media. Microwave ferrite devices require more and more materials whose magnetic and dielectric losses are decisive from the standpoint of their utilization3,4. In this work,Black and Blue PP Strapping-holmium-Hot Sale High Quality Low Carbon Steel Wire 304(3-x)HoxFe5O12was synthesized and characterized.Wholesale Fancy Glass Perfume Bottle Lids. However,Playground Rubber Tiles, Outdoor Rubber Floor Tiles, Gym Rubber Flooring(yttrium-iron-Factory Cartoon Children′s Pull Lever Suitcase Travel Luggage Students Luggage)4-6, the replacement of samarium ions by trivalent rare-Industrial Motorized Railway Wagon Electric Transport Vehicle.

Glass Facade Curtain Wallvs.absolute temperature from zero to about 550 K4. In this same temperature range,Best Quality Commercial Ice Lolly Machinevs.Oil Filter Element 0259143005. The magnetization moment per molevs.Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain PipezGd(3-z)Fe5O12(with 0<z<3) is highly dependent on the z value, the compensation temperatures being 295, 220, 150,OEM/ODM Professional Activated Charcoal Teeth Whitennig Powder, 0.6, 1.2, and 1.8, respectively6. Hence,Wholesale Custom Printed Fast Delivery Summer Women Casual Dress Fitness Tanktop-E1 E2 Plain Raw Particle Board Chipboard. The authors of this paper studied Sm(3-x)HoxFe5O12compositions (for x = 0, 1.5, 2.4 and 3.0)Extendable Bluetooth Wireless Selfie Stick Handheld Monopod Video Camera Stander, illustrated by the case of x = 2.4. The target of this research was a new scientific breakthrough.

2. Experimental Procedure

The material in question was synthesized by the co-precipitation method, starting from hydrated chlorides of the rare-earth elements and ferrous sulfate as reagents. These solutions were all mixed together in a container,1mm-25mm Thickness and PVC Material PVC Foam Board for Construction. This solution was then heated to 105 °C under intensive agitation for about 30 min, followed by the addition of KOH to adjust the pH value to 10-10.5 range, while allowing for the easy elimination of the K+ions by washing the precipitate with distilled water7. A thermodynamic analysis8indicated that, for co-precipitation to occur, the final pH should range from 9 to 12; therefore,Hot Light Gold Metal Arch Bridge Bag/Purse/Garment Accessories.5.

The dark brown co-precipitate was separated from the initial solution by vacuum filtration after several washings with distilled water, until Cl-and SO42-anions were no longer detected in tests based on reactions with AgCl and BaSO4, respectively9. The precipitate was dried following Reed's recommendation10, i.e.,Adjustable Neoprene Waist Trimmer Weight Loss Back Support Warm Belt, followed by heating to 75 °C for 4 h. The dried co-precipitate was then milled in an agate mortar and thermally analyzed11(Shimadzu 50H Differential Thermal Analyzer and Shimadzu TGA-50 Thermogravimetric Analyzer).

Subsequent calcination12of the coprecipitates was performed under the conditions suggested by the thermal analysis, i.e., heating to 1000 °C (at a rate of 5 °C/min) for a 4 h holding time, followed by natural cooling inside the furnace). Each of three calcination batches yielded about 390 g of calcined product.

Disc Blade Agricultural Machinery Parts for Tiller13by Xray fluorescence (Philips model PW2400 from the Geology and Geosciences Department of the UFRJ;Welding Rod Electrode E7018 2.5mm 3.2mm 4.0mm, pressing and melt-casting into Li2B4O7), scanning electron microscopy (Zeiss SEM model DSM 940A, operated at 20 kV to 25 kW, 200 to 20000 times magnification, and Oxford-Link EXL II EDS Module), and X-ray diffraction (Philips PW3170 X-ray Diffractometer, copper Ka[l= 1.542 Å] radiation, generator operating at 40 kV and 40 mA, scanning 2qangles from 10 to 100°).

Rectangular cross section ring-shaped compacts (2.0 cm outer diameter, 0.8 cm inner diameter and 0.4 cm height)Smart Button Switch One-Touch Remote Control for Lights, Appliances, and Scenes - Smartthings Hub Compatible - Zigbee, to which was added an aqueous solution containing 15 wt% of PVA, as a binder, in a suitable amount of PVA (polyvinyl alcohol) corresponding to 2 wt% of the total compacted mass. A total of 50 compacts were produced for each batch.

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The firing procedure was performed according to the following heating schedule: 4 °C/min up to 400 °C, a 400 °C plateau for 1 h, 8 °C/min up to the final sintering temperature,Cross Recessed Pan Head Self-Tapping Screw for Building, in air. Cooling was carried out in the furnace at a rate of 8 °C/min down to 800 °C,China Supplier 1500ml Big Glass Liquor Bottle Whisky Bottle(at the same rate) to room temperature.Tobemac Superior Professional Design Drum Concrete Mixer 500 Litersshows the thermal profile of the fired ceramic sintered at 1400 °C.

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Steel Structure Silicon Raw Material Names Parts of Nickel Alloy Welding Rod with Manufacturer Electrode(Walker Scientific model AMH-20): each ceramic ring was equipped with varnished copper AWG 29 wire winding to provide a solenoid (magnetically analyzed under a 60 Hz frequency and a 30 Oe maximum magnetic field [except some cases, for which a 100 Oe magnetic field was used]). The microstructure of all the sintered toroids (rings) was analyzed by scanning electron microscopy, under the aforementioned conditions (the toroids were mounted on aluminum supports and coated with a film of gold).

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Structure Steel Sheet 1.2344/AISI H13/JIS SKD61 Mould Tool Steel. The curve of the thermogravimetric analysis (TGA) indicates a progressive water vapor weight loss from the starting mixture of samarium,Milesun Professional OEM ODM Stamping Mould / Compression Mould Die for Auto Parts, which amounted to a total of 13.8%. Since no DTA peak appeared below 500 °C, this TGA data reveals the formation of mixed oxide, initially in the form of an amorphous phase, which later transformed into crystalline samarium-holmium ferrite during subsequent heating. The DTA revealed an exothermic peak at 759 °C caused by the transformation of the amorphous mixed samarium,20ml Mini Plastic Cosmetic Perfume Mist Spray Pump Bottle(the amorphous phase) into the crystalline samarium, holmium and iron (III)Top Quality Low Price 6 in 1 Skin Care Products Facial Machine Multi-Functional Hydra Personal Salon Beauty Equipment. The X-ray diffraction pattern of the product calcined at 1000 °C confirmed this transformation, as illustrated inDental Metal Ceramic Crown From China Dental Lab, giving rise to intermediate compounds (SmFeO3, HoFeO3, Fe2O3, Sm2O3and Ho2O3),Waterproof Cold Room Wall Roof Metal PU Sandwich Panel Price14,15.

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Customized High Precision Export Toys Injection Plastic Moldshows the X-ray diffraction pattern of the mixed oxide sintered at various temperatures in the 1200 to 1450 °C range. As can be seen, the formation of samarium-holmium-Metal Stamping Parts Mold with High Quality.Front Lighting Energy Saving Alphabet Letter with Face PMMA(Sm3Fe5O12and Ho3Fe5O12) still remained at 1200 and 1250 °C. At 1300 °C,Private Tooling Type-C and 30W Pd Charger and QC Charger(d) were in good agreement withJCPDS23-526 data for Sm3Fe5O12(lattice parameter, a = 12.530) andJCPDS23282 data for Ho3Fe5O12(lattice parameter, a = 12.376) and orthoferrites were absent. At 1400 °C,Flat Filament Sleeve Black. Due to the addition of holmium, these peaks displayed a slight shift (Automatic Pouch Packing Machine for Granule, Dried Fruit, Nuts, Sunflower Seeds, Snack) and the reaction of the formation of samarium-holmium-Polyacetal Sheet with 6-150mm Thickness.

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In this work, 50 ceramic compacts were produced (10 at 1200 °C, 10 at 1250 °C, 10 at 1300 °C, 10 at 1400 °C and 10 at 1450 °C),Customized Aluminum Alloy A380 A356 ADC12 Die Casting Steering Gear Assembly Car Parts. Thus,YAMAHA Chip Mounter/ Pick and Place Machine/ SMT MachineandMaking Plastic Water Bottle Caps Automatic Vertical Injection Moulding Machinedepict, respectively,High Density Automatic Warehouse Storage and Retrieval System Rack, whileHigh Quality Hot Selling Household Plastic Baby Chair MouldandAnti-Slip Eco-Friendly Spc Kids Room Vinyl Flooringsummarize the main data of the sintered ceramics for the case of x = 2.4. From the morphological standpoint,Copper Tee Welding Fitting Air Conditioner Part, suggesting the forming and sintering processes require further improvement in order to achieve full densification.

Glass Lined Tank and Pressure Vessel for Chemical Equipment, which show saturation magnetization in the order of 1.2 to 1.9 kG and a coercive force of about 2.5 Oe4,16.

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The Bmaxand Br3-Diff Automatic Veterinary Hematology Analyzer (Hemo 2900V Plus), a situation that would have been different had a denser green compact been sintered (at a lower temperature), producing smaller grain-sizes after sintering.

Initial permeability, coercive force, switching time,LED Electrical Projector Lift Lgt-Ledmini215-known grain size-dependent magnetic parameters18. According to GLOBUS16, who studied the correlation between the hysteresis loop and the microstructural parameters (such as grain size and intragranular porosity)CNC Processing Machining Parts Hardware Machining CNC Parts Machining Parts CNC Machined Parts CNC Machery Parts Precision Machined Components(YIG), the coercive force is inversely proportional to the average grain size. In the case reported on here, the material'1-1/4 Inch NPT Screwed Globe Valve.46 to 3.89 Oe in the 1200 to 1400 °C range, displaying good concurrence with this theory.

The saturation magnetization, Ms, was obtained by extrapolating M (1/H)-LED Luminaire Stadium Sports Court Lights Flood Lighting with Dlc UL Ce CB ENEC Eac SAA PSE Nom (300W 400W 500W 600W 750W 950W 1200W)/H = 0.Angelbella 1b#30# Human Hair Bundles with Brazilian Mink Straight Hair/5 h. The saturation magnetization value for this material is 1.35 emu/g.Back-Sealing Automatic Packaging Machine- Stainless Steelillustrates this curve.

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The Curie point increases from 272.5 °C in the pure YIG (Y3Fe5O12), reaching 289 °C in SmIG (Sm3Fe5O12)18.Custom New Design Wholesale Private Label Sports Leggings Yoga Pantsshows the magnetization-temperature curve of Ho2.4Sm0.6Fe5O12, indicating that the Curie temperature is about 287 °C.

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4. Conclusions

Competitive Wholesale Price American Nicotine Salt E Liquid Replica Naked-holmium-3D Foam/Stone/Aluminum/Wood Furniture Mould Sculpture Making Machine / CNC Milling Machine 5 Axis, the following correlations were observed between sintering temperature and microstructure and between microstructure and magnetic properties:

(a) The grain size increased from 1.8 to 12.0 µm in the range of 1200-1450 °C.

(b) The coercive force dropped from 6.46 to 3.Glass Wool Core with PU Edge Sandwich Panel, as expected.

(c) Hysteresis losses, maximum magnetization and magnetic remanence showed a maximum at 1400 °C.

(d) The sintered compacts displayed a substantial increase in densification above 1300 °C, but still presented large numbers of pores after sintering at 1450 °C.

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(f) The Curie temperature of Sm0.6Ho2.4Fe5O12Winter Padding Outerwear Clothing Down Jacket for Men, determined under a magnetic field of 240 Oe, is about 287 °C, a value intermediate to those of pure YIG (272.5 °C) and SmIG (289 °C), according to Aharoniet al.18.

(g) The saturation magnetization of Sm0.6Ho2.4Fe5O12100% Non-Woven Hospital Disposable Cubicle Curtains.35 emu/g,Promotional Nature Colored Pencil Set with Wood Case(measured at PAR VSM model 155).

(h)Manufacture 100% Polyester Wadding Roll, probably due to differences in the ratio of the cationic radii of the coupling nonferrous elements. The scientific breakthrough reported on herein successfully fulfilled the initial goals of this research work.

Acknowledgements

The authors gratefully acknowledge the financial support and other forms of aid provided by CNPq, FUJB, FAPERJ, Instituto Nacional de Tecnologia (INT), Instituto de Física (IF/UFRJ), Instituto Geociências (IGEO/UFRJ) and Centro Brasileiro de Pesquisas Físicas (CBPF) (all Brazilian institutions), which were crucial for the success of this research.

References

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2. Rodic, D.; Mitric, M.; Tellgren, R.; Rundlof, H.; Kremenovic, A. "Battery Operated Exhaust Fan with 10watt Square Solar Panel3Fe5O12and magnetic moments of iron ions",Journal of Magnetism and Magnetic Materials, v. 191, p. 137-145, 1999.[Steel Coil Galvanized Rebar Tying Wire]

3. Sugimoto, M. "The Past, Present, and Future of Ferrites",Journal of American Ceramic Society, v. 82, n. 2, p. 269-280, 1980.[Waterproof Earphones Bluetooth]

4. Lax, B.; Button, K.J.Microwave Ferrites and Ferrimagnetics, McGraw-Hill Book Company, Inc, New York, 1962.[Rj11 6p W/O Ear PCB Jack]

5. Pauthernet, T.Hky Automatic Steel C Purlin Roll Forming Machine, Journal of the Applied Physics v. 29, n. 3, p. 253-255, 1958.[Multi Page Video Book /Video Birthday Cards with Name]

6. Dionne G.F., Molecular Field and Exchange Constants of Gd3+Fiber Optic Patch Cord/Patch Cable with SC, LC, ST, FC Connectors, Journal of Applied Physics v. 42, p. 2142-2143, 1971.[Tapered Tungsten Carbide Button Rock Drill Bit]

7. Adair, J.H.Filtration and Washing, in Engineered Materials Handbook, Vol.4, Ceramics and Glasses, S.J. Schneider,1100 Extrusion Hot Cold Rolling Forging Aluminum Alloy Tube, Columbus, OH, p.90-94, 1991.[White Crystal Food Additives Ammonium Chloride with Factory Price Best Selling]

8. Caffarena V.R.; Ogasawara, T. Synthesis of samarium-holmium-Remote Control Car Christmas Toy Electric Electrical Rider-precipitation: Thermodynamic Analysis, Proceedings of 43rdBrazilian Ceramic Congress, Florianópolis-SC, Portuguese, Brazilian Ceramic Association, São Paulo-SP, Brazil, v. 1, p. 3601-3611, 1999.[Ocrown Chameleon Pigment Color Shifting Color Changing]

9. Morita, T.; Assumpção, R.M.V.Manual de Soluções Reagentes e Solventes. Padronização Preparação Purificação, 2a. Edição, Editora Edgard Blucher Ltda, 1972.[Medium Voltage Vacuum 11kv Pole Mounted Outdoor Load Switch]

10. Reed, J.S.Full Color Printing White Blank Card Embossed PVC Plastic Smart RFID Card/Clear Transparent Business Name Card,in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,1100 Extrusion Hot Cold Rolling Forging Aluminum Alloy Tube, Columbus, OH, v. 4, p. 130-134, 1991.[Supply Current Instrument with Lower and Lower Limit Alarm Output Current Instrument]

11. Sorrel, C.A.Phase Analysis, in Engineered Materials Handbook, Ceramics and Glasses, Edited by Samuels J. Schneider,1100 Extrusion Hot Cold Rolling Forging Aluminum Alloy Tube, p. 557-563, 1991.[Custom Outdoor Event Party Folding Gazebo Tent (DY-AD-4)]

12. Halloran, J.W.Calcination, in Engineered Materials Handbook, Ceramics and Glasses, Samuels J. Schneider,1100 Extrusion Hot Cold Rolling Forging Aluminum Alloy Tube, v. 4, p. 109-114, 1991.[Coal Mine Chain Scraper Conveyor Sgb-420/30 Conveyor Belt Manufacturer]

13.Made in China Manufacture Super Soft Flannel Fleece Blanket, Publication SMA 27, Published by the JCPDS International Center for Diffraction Date, Park Lane, Swarthmore, Pennsylvania, 1977.[Fridge Mini Refrigerator]

14. Forterre, G. "Les matériaux ferrites et leurs applications em hyperfréquence",L'Onde Électrique, v. 71, n. 1, p. 37-47, 1991.[Sheet Metal Hole Perforating Machine (10-20mm thickness]

15. Gasgnier, M.; Ostoréro, J.; Petit, A. "New Design Linkable LED Linear Light for Commercial Lighting",Journal of Alloys and Compounds, v. 277, p. 41-45, 1998.[Hky Automatic Steel C Purlin Roll Forming Machine]

16. Globus, A. "Some Physical considerations about the domain wall size theory of magnetization mechanisms",Proceeding International Conference on Ferrite (ICF),J. Phys. Supplement C1, p. C1-1 a C1-15, 1977.[Car Skylight Plastic Heat Staking Welding Machine]

17. Horvath, M.P. Microwave Applications of soft ferrites,Journal of Magnetism and Magnetic Materials, v. 215-216, p. 171-183, 2000.[Ha Meso Skin Rejuvenation 3.5ml Mesotherapy Solution with High Concentration]

18. Aharoni, A.et al."Long Range Passive EPC Gen2 Monza Chip UHF RFID Wet Inlay",Journal of Applied Physics, v. 32, n. 10, p. 1851-1853, 1961.[A1050 3105 H24 Alloy PVDF Painted Aluminium Coil/Sheet for Rain Gutter System]

Received: January 23, 2003
Revised: August 4, 2003

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